This study analyzes the effect of public-private partnership for reduction of concentration of benzene that is emitted from Ulsan petrochemical complex. Despite the fact that from 2012 to 2016 each factory had been observing legal standards, according to measurements of concentrations of benzene by the monitoring station in Yeocheon-dong, Ulsan, for five successive years, benzene concentrations had been exceeding the environmental standards for air quality ($5{\mu}g/m^3$) by 1.4 to 1.8 times, resulting in endless civil petitions. On the other hand, in 2017, when a cooperation system was constructed across private, public and research institutions and actors, through the formation of a network for information-sharing among, and professional education to reinforcement of competency among the Ministry of Environment, the National Institute of Environmental Research, conglomerates, and local businesses of Ulsan, Benzene concentration became $4.25{\mu}g/m^3$, satisfying the atmosphere environmental standard. According to the analysis, cooperation built based upon mutual trust between the public sector and the civil sector has made it possible to solve, in a year, the regional environmental problem, i.e., excessive benzene concentrations for 5 years. Henceforth, along with research on measures to share and spread out advanced technology and case-studies, targeting other regions where benzene concentrations have not yet improved, research on methods to maintain benzene concentrations as they are is needed.