Recently, constructions of huge reinforced concrete structures such as nuclear power stations have been increased. When massive concrete is placed, cracking due to the hydration heat of cement is recognized as a major problem. The development of thermal stress is influenced by the structure shape and the constraint conditions, and cracks usually occure from tensile stresses which developed due to temperature drop. In this study a protocol specimen is made to examine the distribution of temperature and thermal stress of reaction wall of Daewoo Institute Construction Technology. The size of the specimen is made by considering minimum size of real structure. In this study, concrete strain gauge, concrete stress gauge, concrete non-stress gauge, and thermocouples, are instrumented to measure thermal stress in massive concrete structure. A new measuring technique is proposed to calculate thermal stress.