In this study, we analyzed probability distribution of EMCs (Event Mean Concentration) of COD, TOC, T-N, T-P and SS from rice paddy fields and compared the mean values of observed EMCs and the median values of estimated EMCs ($EMC_{50}$) through probability distribution. The field monitoring was conducted during a period of four crop-years (from May 1, 2008, to September 30. 2011) in a rice cultivation area located in Emda-myun, Hampyeong gun, Jeollanam-do, Korea. Four probability distributions such as Normal, Log-normal, Gamma, and Weibull distribution were used to fit values of EMCs from rice paddy fields. Our results showed that the applicable probability distributions were Normal, Log-normal, and Gamma distribution for COD, and Normal, Log- Normal, Gamma and Weibull distribution for T-N, and Log-normal, Gamma and Weibull distribution for T-P and TOC, and Log-normal and Gamma distribution for SS. Log-normal and Gamma distributions were acceptable for EMCs of all water quality constituents(COD, TOC, T-N, T-P and SS). Meanwhile, mean value of observed COD was similar to median value estimated by the gamma distribution, and TOC, T-N, T-P, and SS were similar to median value estimated by log-normal distribution, respectively.