유기황화합물-Polyphenylenediamine리튬전지용 정극의 전기적특성

Electrical Characterization of Organo Sulfur Compound-Polyphenylenediamine Positive Electrode in Lithium Battery

  • 박수길 (충북대학교 공대 공업화학) ;
  • 박종은 (충북대학교 공대 공업화학과) ;
  • 손원근 (한국화학 연구소) ;
  • 김상욱 (서울시립대 화학공학과) ;
  • 임기조 (충북대학교 공대 전기공학과) ;
  • 이주성 (한양대학교 공대 공업화학과)
  • 발행 : 1997.04.01

초록

Polyphenylenediamine(PPD)film was prepared with organo sulfur compond (2-aminothiophenol, 1,2-ethanedithiol, and 2-aminoethaneethiol etc.) adding lithium salt to increase the electrical conductivity of the polymer surface. The molecular structure of conductive polymer synthesized were examined and discussed by using SEM, FT-IR, NMR etc. The elecrical conductivity messurement were carried out with four-probe method at dry box of He and $N_2$atmosphere. The typical value of successful electrical conductivity was 1.2$\times$10$^1$S/cm at room temperature.

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