Epoxy-siloxane IPN의 열적 안정성에 미치는 후기경화의 영향

Effects of Post-curing on Thermal Stability of Epoxy-sioxane IPN Structure

  • 조영신 (서울시립대학교 화공과) ;
  • 심미자 (서울시립대학교 생명과학과) ;
  • 김상욱 (서울시립대학교 화공과)
  • 발행 : 1999.11.20

초록

The thermal stability of the post cured epoxy-polysiloxane IPN structure was observed by using DSC and TGA. As the post curing time increased the glass transition temperature increased and the secondary exothermic peak disappeared. The thermally decomposing activation energy calculated by using Kissinger expression was 225.6 kJ/mol. The thermal stability of the grafted IPN of epoxy and silicon compound depends on the composing ratio and post curing conditions of time and temperature.

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