펜톤유사산화반응을 이용한 4-Chlorophenol 분해과정 예측

The batch experiments showed that 0.515mM 4-chlorophenol and its oxidation intermediates could be totally decomposed within 60 minutes by 1g/L steelers' dust and 0.485mM hydrogen peroxide at pH 2.7. The rate constants in the simplified kinetic model proposed in this study were estimated by fitting to the experimental data obtained in $H_2O$$_2$/steelers' dust system. Using the estimated kinetic rate constants, the simulation of 4-chlorophenol, ferrous iron, hydrogen peroxide, and hydroxyl radical concentration was performed. The predicted concentrations of 4-chlorophenol and hydrogen peroxide corresponded to the actual concentrations.