Properites of Inorganic Hybrid Silica Materials according to the XRD patterns

XRD 패턴에 따른 유무기복합 화합물의 특성

  • 오데레사 (제주대학교 전기전자공학부 및 첨단기술연구소) ;
  • 고유신 (제주대학교 전기전자공학부 및 첨단기술연구소) ;
  • 김경식 (제주대학교 전기전자공학부 및 첨단기술연구소)
  • Published : 2003.07.01

Abstract

This paper reports the correlation between dielectric constant and degree of amorphism of the hybrid type Si-O-C thin films. Si-O-C thin films were deposited by high density plasma chemical vapor deposition using bistrimethyl- silylmethane(BTMSM, $H_{9}$C$_3$-Si-C $H_2$-Si-C$_3$ $H_{9}$) and oxygen precursors with various flow rate ratio. As-deposited film and annealed films at 40$0^{\circ}C$ were analyzed by XRD. The Si-O-C thin films were amorphous from XRD patterns. For quantitative analysis, the diffraction pattern of the samples was transformed to radial distribution function by Fourier analysis, and then compared with each other. The degree of amorphism of annealed films was higher than that of as-deposited ones. The dielectric constant varied in accordance with flow rate ratio of precursors. The lowest dielectric constant was obtained from the as-deposited film which has the highest degree of amorphism after annealing.

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