Synthesis and Characterization of Acrylic Polymer Containing Silk Protein

  • Zhongmin Chen (Department of Functional Polymer Science, Faculty of Textile Science and Technology, Shinshu University) ;
  • Kim, Mutsumi ura (Department of Functional Polymer Science, Faculty of Textile Science and Technology, Shinshu University) ;
  • Masahiro Suzuki (Graduate School of Science and Technology, Shinshu University) ;
  • Yoshiyuki Kondo (Department of Functional Polymer Science, Faculty of Textile Science and Technology, Shinshu University) ;
  • Kenji Hanabusa (Graduate School of Science and Technology, Shinshu University) ;
  • Hirofusa Shirai (Department of Functional Polymer Science, Faculty of Textile Science and Technology, Shinshu University)
  • Published : 2003.10.01

Abstract

Three kinds of acrylic polymers containing silk protein were synthesized, which are (1) blending of silk fibroin (SF) fiber and polyacrylonitrile (PAN); (2) graft-copolymer of PAN onto SFs; (3) random-copolymer synthesized by copolymerization of acrylonitrile (AN) and silk fibroin peptide (SFP) with vinyl groups, and their solubility, thermal property, and moisture absorption was investigated, respectively. These polymers have difference solubility and attributable to their structure. Their excellent thermal stabilities and better moisture absorptions were indicated.

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