한국정보디스플레이학회:학술대회논문집

The Korean Infomation Display Society (한국정보디스플레이학회)
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Stable blue light emitting polyfluorenes with good solution processibility

  • Hwang, Do-Hoon (Dept. of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Lee, Ji-Hoon (Electronic Materials Lab. Samsung Advanced Institute of Technology)
  • Published : 2003.07.09
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Abstract

New polyfluorene derivatives, poly[9,9-bis(4' n-octyloxyphenyl)] fluorene (PAPF-8) and poly[9,9-bis(4'-(2",7"-dimethylocyloxy)phenyl)] fluorene (PAPF-10) were synthesized from the monomers, 2,7-dibromo-9,9-bis[4' (2"-ethylhexyloxy)benzene] fluorene and 2,7-dibromo-9,9-bis[4' (2", 7"-dimethyloctyloxybenzene)] fluorene through the Ni(0) mediated polymerization. The copolymers were characterized using FT-IR spectroscopy, UV-vis spectroscopy, TGA, photoluminescence (PL) & electroluminescence (EL) spectroscopy, elementa analysis, and molecular weight studies. The synthesized POPF-8 and POPF-10 showed a pure blue emission without any spectral change upon thermal annealing and EL device operation.

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