표준시료를 이용한 토양중 중금속 분석방법 비교

The heavy metal analysis (Cd, Pb, Cu, Cr, Zn, Ni) with various extraction methods was performed using the certified sample and real soil sample. In case of the certified samples, $10.5{\sim}118%$ of recovery was showed with various ranges depend on the metal kinds and extraction methods. Also, the alkali-digestion method was showed the proper results by applying in hexavalent chromium. In case of real sample, compared to amounts of heavy metals extracted using 0.1N-HCl, those extracted using acid digestion are higher by $3{\sim}24$ times in Cu, $1.1{\sim}1.5$ times in Cd, $2{\sim}23$ times in Pb, $3{\sim}104$ times in Zn, $12{\sim}101$ times in Ni, $30{\sim}202$ times in Cr. There is no considerable difference between four acid digestion methods.