Nanoscale Charge Transport in P3HT:PCBM:Gold Nanoparticle Composite Materials for Polymer Solar Cell Application

  • Nguyen, Thuc-Quyen (Department of Chemistry and Biochemistry, University of California) ;
  • Dante, Mark (Department of Chemistry and Biochemistry, University of California) ;
  • Peet, Jeffrey (Department of Chemistry and Biochemistry, University of California) ;
  • Bazan, Guillermo (Department of Chemistry and Biochemistry, University of California)
  • Published : 2006.10.13

Abstract

Recently, conjugated polymer solar cells have attracted a great deal of attention. In this work, we applied the various scanning probe techniques to characterize composite materials typically used to fabricate polymer solar cells: poly-3(hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and P3HT/PCBM/Au nanoparticle (NP) samples. The latter is studied due to the idea of using the gold NP surface plasmon to enhance the optical absorption of the composite films. AFM is used to characterize the film morphology whereas conducting AFM is used to study the charge transport properties at the nanoscale. We found that there is a direct correlation between the nanoscale charge transport measurements and the device efficiencies.

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