Proceedings of the Polymer Society of Korea Conference (한국고분자학회:학술대회논문집)

The Polymer Society of Korea (한국고분자학회)
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Template polymerization of multi-vinyl monomer with poly(2-hydroxyethyl methacrylate) backbone

  • Saito, Reiko (Dept. of Org. and Polym. Mats., Tokyo Institute of Technology) ;
  • Yoko, Kazutaka (Dept. of Org. and Polym. Mats., Tokyo Institute of Technology) ;
  • Iijima, Yuki (Dept. of Org. and Polym. Mats., Tokyo Institute of Technology)
  • Published : 2006.10.13
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Abstract

Multi-vinyl monomer, which contains many vinyl groups in a molecule, was prepared by esterification of hydroxyl groups of poly(2-hydroxyethyl methacrylate) with methacryloyl chloride. Then, copper-mediated atom transfer radical polymerization was carried out as a template polymerization. The propagation of polymerization was investigated by kinetic analysis.

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