A simulation study on synthesis gas process optimization for FT(Fischer-Tropsh) synthesis

FT(Fischer-Tropsh) 합성유 제조를 위한 합성가스 공정 최적화 연구

  • 김용헌 (한국석유공사 석유개발연구원) ;
  • 이원수 (한국에너지기술연구원) ;
  • 이흥연 (한국에너지기술연구원) ;
  • 구기영 (한국에너지기술연구원 수소에너지연구센터) ;
  • 송인규 (서울대학교 화학생물공학부)
  • Published : 2009.06.25

Abstract

A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

Keywords