Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Charge-Transfer Complex Formation of Amines with Organic Halides (II) Complex Forming Tendency by Various Electron Acceptors

아민과 有機할로겐 化合物間의 Charge Transfer Complex 形成에 關한 硏究 (II) Electron Acceptor 에 따른 Charge Transfer Complex 形成能에 關한 硏究

  • Kim, Yoo-Sun (Atomic Energy Research Institute, Chemistry Division) ;
  • Oh, Jung-Hee (Atomic Energy Research Institute, Chemistry Division)
  • 김유선 (原子力硏究所 化學硏究室) ;
  • 오정희 (原子力硏究所 化學硏究室)
  • Published : 19671200
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Abstract

Various amines (Triethylamine, Diethylamine, Dimethylaniline, Pyridine and Diphenylamine) and electron acceptors (Carbontetrachloride, iodine monochloride and iodine) were reacted in the hexane solvent system to form a charge transfer complex in each case. The tendency of forming a charge transfer complex by these electron acceptors was proportional to the basicity of amines and the different type of complex was formed as the polarity of electron donor had markedly changed, which were identified by ultraviolet spectrophotometry. A correlation between the formation of complex and the basicity of amine and the polarity of electron acceptor was discussed.

各 種 아민(triethylamine, diethylamine, pyridine, diphenylamine, dimethylaniline)과 各種 Electron Acceptor($CCl_4,\;ICl,\;I_2$)를 Hexane 溶媒 存在下에서 作用시킨 結果 各各 Charge Transfer Complex를 形成하였으나 그 形成能은 아민의 Basicity에 比例하였고 Electron Donor의 Polarity의 差가 클 때에는 다른 形式의 Complex를 形成함을 紫外線 吸收 分光法으로 確認하였다. Complex 形成能과 아민의 Basicity 및 Electron Acceptor의 Polarity의 關係를 論하였다.

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References

  1. J. Am. Chem. Soc. v.81 N.J. Rose;Russel S.
  2. Bull. Chem. Soc., Japan v.33 H. Yada;J. Tanaka;S. Nagakeisa
  3. Acta. Chem. Scand. v.15 O. Hassed;H. Hope
  4. J. Korean Chemical Society v.10 S. U. Choi(et al.)
  5. J. Am. Chem. Soc. v.84 D.P. Stevenson;G.M. Coppinger
  6. J. Am. Chem. Soc. v.88 S. Kobin(et al.)
  7. J. Inorg. & Nucl. Chem. v.17 R.D. Whittaker, Jr.;C.W. Hickman;J.R. Ambnase
  8. This Journal v.11 Y.S. Kim;J.H. OH