Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Partial Molal Volumes of Anilinium Chloride in Isopropanol-Water Mixtures

2-프로판올-물 혼합 용액에서의 염화아닐린늄의 분몰랄 부피

  • Cho, Byung-Rin (Dept. of Chem. Eng., Inha Inst. of Technology) ;
  • Lee, Young-Ja (Dept. of Chem. Eng., Inha Inst. of Technology) ;
  • Lee, Ik-Choon (Dept. of Appl. Chem., College of Eng., Seoul National University)
  • 조병린 (인하공과대학 화공과) ;
  • 이영자 (인하공과대학 화공과) ;
  • 이익춘 (서울대학교 공과대학 응용화학과)
  • Published : 19690900
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Abstract

Determination of partial molal volumes of anilinium chloride isopropanol-water mixtures at 30.00$^{\circ}$showed a distinct minimum at 0.20 mole fraction isopropanol. This was interpreted as maximum in electrostriction effect and minimum in water structure. The depth in $\bar{V}^{\circ}$for alcohol-water mixtures was in the order MeOH > i-PrOH > EtOH, which indicated the importance of microscopic structure around ions.

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References

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