참고문헌
- Fuel v.41 no.5 R. D. Hartley
- Fuel v.38 Dobinson
- 大韓化學會誌 v.12 金源澤
- 大韓化學會誌 v.13 金源澤
- 大韓化學會誌 v.13 金源澤
대한화학회지 (Journal of the Korean Chemical Society)
- 제16권5호
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- Pages.320-327
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- 1972
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- 1017-2548(pISSN)
- /
- 2234-8530(eISSN)
土炭흄酸의 性狀 및 應用에 關한 硏究 (第4報) 아조染料 製造에 관하여
Studies on the Characteristics of Humic Acid and its Utilizations (Part 4). Manufacturing of Azo-dyes from Humic Acid
- Han Kyoungsuk (Department of Polymer Technology, College of Engineering, Hanyang University) ;
- Kim, Won Taek (Department of Polymer Technology, College of Engineering, Hanyang University)
- 발행 : 1972.10.30
초록
韓國産 土炭의 흄酸의 性狀(分子量, 分子式 및 示性式)과 基應用(田沓用 土壤改良制 및 溶性燐質 肥料製造)에 關해서 이미 硏究報韓 바가 있으나, 흄酸의 構造를 推定하는데 있어서, 未及한 鮎이 있어서, 이의 補完策으로서 aromatic diazonium salt를 coupling 시켜, phenolic-OH group 의 結合狀態를 살펴보고 各種 aromatic diazonium salt와 흄酸 및 니트로흄酸에 依해서 얻어진 生成物들을 Azo 染料로 利用함으로서 應用策의 一環을 講究했다.
The coupling of aromatic diazonium salts with humic or nitrohumic acid, as a supplemental method of determining the structure and utilization of humic acid, were studied. The following results were obtained. 1) Humic acids have many vacan to-and p-positions in their phenol kernels. 2) Humic acids have not so many benzene kernels in their structure units. 3) When coupled with aromatic diazonium salts (such as aniline, aminonaphthalene and aminoanthraquinone derivatives), various azo-dye were obtained.
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