Formationof Mullite and Effect of $TiO_2$ on Mullitization

물라이트합성과 $TiO_2$ 의 효과에 관하여

  • 모경화 (한국과학기술연구소 요업재료연구실) ;
  • 정병진 (한국과학기술연구소 요업재료연구실) ;
  • 장성도 (한국과학기술연구소 요업재료연구실)
  • Published : 1976.12.01

Abstract

Mullite was synthesized by using kaolin and $\alpha$-alumina, and halloysite and aluminum hydroxide as raw materials at the various temperature in the range of 1200$^{\circ}$-1750$^{\circ}$C. The degree of mullitization was measured respectively by a quantitative X-ray diffraction method and a chemical analysis method. The rate and the maximum degree of mullitization were found to increase with temperature . The reaction completed at 1600$^{\circ}$Cfor less than 30 minutes, and yielded 98% mulllite inpurity in the case of kaolin-Al(OH)3. TiO$_2$ up to 3% was added to the batches of kaolin-Al(OH)$_3$. the effect of addition on the mullitization was investigated and found to decrease the sintering temperature for the mullitization. The mechanism of TiO$_2$ addition on the formation of mullite was also discussed.

Keywords

References

  1. Mullite, It's structure, formation and significance Janos Grofcsik
  2. J. Am. Ceram. Soc. v.25 no.1 Catalytic Mullitization of Kaolinite by Metallic oxide Parmelee;Rodriguez
  3. J. Am. ceram. soc v.31 no.9 Mullitization of Kaolinite Comeforo;Fischer;Bradley
  4. J. Am. Ceram. Soc. v.42 no.7 The Kaolinite-Mullite Reaction Series:Ⅰ, Ⅱ, and Ⅲ Brindley;Nakehira
  5. Reactions between Mullite and Glassy phase in Porcelains K.H. Schuller
  6. The Mechanical Properties of High alumina Refractories utilizing Various Bonding Agents Rigby
  7. Caculation of the Theoretical Disorder Entropics of the Intermediate Phases formed during Thermal Transformations of Aluminosilicate Minerals Mackenzie;Duncan
  8. J. Am. Ceram. Soc. v.55 no.11 Synthesis and Mechanical Properties of Stoichiometric Aluminum Silicate(Mullite) Mazdiyasni;Brown
  9. Refractories v.19 T. Hirata
  10. Refractories v.21 Y. Maeda;T. Hirata
  11. Nagoya Gijutsu Shikensko Hokoky v.4 no.11 Quantitative Determination of Mullite and Corundum in High-Alumina Porcelain Bodies Okuda
  12. Infrared Kinetic Study of the High Temperature reactions of Synthetic Kaolinite Mackenzie
  13. J. Am. Ceram. Soc. v.52 no.2 Kinetics and Mechainsm of High Temp. Reactions of Kaolinite Minerals Dunkan;Maekenize;Foster
  14. J. Am. Ceram. Soc. v.42 no.7 The Kaolin-Mullite Reaction Series G.W. Brindley;M. Nakahara
  15. Am. Min. v.39 no.3-4 High Temp. forms from Kaolinite and Halloysite M.D. Glass
  16. Ceramic Bulletin v.51 no.7 Mullitization of Alumino-Silicate Gels McGee;Wirkus
  17. Ogneupory v.9 no.55-58 A review of methods of synthesizing mullite V.M. Grosheva;V.M. Panasevich;I.G. Donet
  18. Arch. Eisenhuttenw. v.29 no.8 Additive Experiments on Synthetic Mullite and Substitution Experiments with Gallium Oxide and Germanium Dioxide, Ⅱ Gunter Gelsdorf
  19. J. Am. Ceram. Soc. v.43 no.5 X-Ray Study of the Solid Solution of TiO₂, Fe₂O₃, and Cr₂O₃ in mullite Murthy;Hummel
  20. Trams. Brit. Ceram. Soc v.51 The System Al₂O₃-TiO₂-SiO₂ M. Agamawi;J. White
  21. High Temp. Oxide M. Douglas Beals;A.M. Alpei(ed.)