Determination of Surface Diffusivities of Oxides by the Combined Sintering

소결에 의한 산화물촉매의 표면확산계수의 측정

  • Published : 1977.02.01

Abstract

The surface diffusion coefficients for nickel, nickel oxide, cuppric oxide, cobalt oxide, alumina and ferric oxide have been determined at various temperatures using the sintering technique. This investigation is based on the model accounting for the sum of the contribution of volume and surface diffusion to the overall shrinkage rate during the initial stage of sintering. Simultaneous measurements of shrinkages and shrinkage rates of the materials compacts were conducted for various annealing times, the results of which were then correlated to the diffusion coefficient.

Keywords

References

  1. J. Appl. Phys. v.28 no.339 Theory of Thermal Grooving W.W. Mullins
  2. J. Appl. Phys v.30 no.77 Flattening of a Nearly Plane Soild due to Capillary W.W. Mullins
  3. Surface Sci. v.42 no.552 Adsorption on Heterogeneous Surfaces W. Rudzinski;M. Jaroniec
  4. Surface Sci. v.36 no.205 Application of thermal Desorption Methods in studies of Catalysis W.L. Winterbottom
  5. Progress Toward the a Priori Determination of Catalytic Properties AIChE v.221 J.B. Butt
  6. Z. Physik Chem. Nene Folge v.89 no.47 Concurrent Measurement of Surface and volume diffusion coefficients in the Ni-Al spinel formation reaction S.K. Moon;W. Komatsu
  7. J. Appl. Phys. v.45 no.9 Monte Carlo Simulation of the kinetics of heterogeneous nucleation A.I. Michaels;G.M. Pound;F.F. Abraham
  8. J. Appl. Phys. v.41 no.3202 Diffusion of Copper in Nicked Single Crystals H. Helfmeier;M.F. Kniepmeier
  9. Material Science Research v.3 no.49 W.M. Robertson;R. Chang
  10. Trans. AIME v.245 no.1291 Surface Self-Diffusion of Nicked B. Mills;P. Douglas;G.M. Leak
  11. Trans. AIME v.185 no.169 Self-Diffusion in Sintering of Metallic Particles G.C. Kuczynski
  12. Kagaku Sosetsu no.9 Diffusion Y. Oishi;K. Ando
  13. J. Appl. Phys. v.42 no.5316 Diffusion of Silver into Nickel Single Crystals A.R. Wazzan;D. Tung;L.B. Robinson
  14. Kagaku Sosetsu no.9 W. Komatsu;T. Shimodairs
  15. Diffusion in Soild P.G. Shewmon