Korean Journal of Fisheries and Aquatic Sciences (한국수산과학회지)

The Korean Society of Fisheries and Aquatic Science (한국수산과학회)
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THE EFFECT OF PROESSURE ON THE ELECTRICAL CONDUCTIVITY OF SEA WATER ( II ) -The Activation Energy and the Activation Volume Change-

해수의 전기전도도에 미치는 압력의 영향 ( II ) -활성화에너지와 활성화부피변화-

  • HWANG Kum-Sho (National Fisheries University of Busan) ;
  • HWANG Jung-Ui (College of Liberal Arts and Sciences Kyungpook National University)
  • Published : 1977.12.01
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Abstract

In this study, physical and chemical properties of sea water were investigated qualitatively from the data measured by means of the conductive method as described in the previous paper. The activation energy, ${\Delta}E$, calculated from the suggested equation describing the electrical conductive property of sea water was about 3.0 to 4.0 Kcal/mole at a given pressure and concentration. The average values of the activation volume change, ${\Delta}V$, over the pressure 1 to 1,200 bars decreased from -1.30 to $-0.27\;cm^3/mole$ as the temperature increased from 10 to $25^{\circ}C$.

제 1보에서 측정한 해수의 비전도도 값을 사용하여 본 논문에서 저자들이 제안한 식으로부터 얻어진 당량 전도도를 Arrhenius plot 했을 때 활성화에너지, ${\Delta}E$는 압력 및 농도변화에 따라 $3.0\~4.0\;Kcal/mole$ 범위 이었다, 압력변화에 따른 활성화 부피변화의 평균치 측정된 온도와 압력에서 $-0.27\~-1.30\;cm^3/mole$ 범위였다. (염소량이 $6.228\%_{\circ},-1.65\~\;-0.32cm^3/mole;\;9.063\%_{\circ},\;-1.18\~-0.27cm^3/mole;\;11.628\%_{\circ},\;-1.53\~-0.07cm^3/mole;\;14.311\%_{\circ},\;-1.37\~-0.35cm^3/mole;\;16.408\%_{\circ},\;-1.18\~-0.47cm^3/mole;\;19.372\%_{\circ},\;-1.53\~-0.29cm^3/mole$)이들값으로 해수의 성질과 물의구조를 정성적으로 밝힐 수 있었다. 본 논문 정리를 위해 조언하여 주신 원중훈교수님께 감사드립니다.

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