The Synthesis of Anorthite by Addition of Flux

Flux 첨가에 의한 Anorthite 합성에 관한 연구

  • Ahn, Young-Pil (Dept. of Inorganic Materials Engineering Han Yang Univ) ;
  • Choi, Suk-Hong (Dept. of Inorganic Materials Engineering Han Yang Univ) ;
  • Lee, Kwang (Dept. of Chemical Engineering Kyung Nam Univ)
  • 안영필 (한양대학교 공대 요업과) ;
  • 최석홍 (한양대학교 공대 요업과) ;
  • 이광 (경남대 화공과)
  • Published : 1979.02.01

Abstract

The Anorthite is useful compound for some ceramic industries but it is difficult to produce Anorthite because of its high melting point (1553$^{\circ}C$) and narrow firing range. On this study, glass frit was added to Anorthite batch composition to widen firing range and lower melting point. After mixing a glass frit $(Na_2O-CaO-6SiO_2)$ with Anorthite, it was melted and quenched. Ratio of Anorthite vs. glass frit was 9 : 1, 8.5 : 1.5, 8 : 2, 7.5 : 2.5, 7 : 3. In those batch composition added amount of $No_2O$ were between 1.3wt.% and 3.9wt.%. To find the thermal change of the quenched, D.T.A. was surveyed. The quenched were fired at various vitrification temperature and detected by X-Raydiffraction analysis. With addition of glass frit, firing range and vitrification temperature of Anorthite was 100~15$0^{\circ}C$ and 1050~115$0^{\circ}C$ respectively. Optimum amount of glass frit was 20wt.% for the upper mentioned.

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References

  1. 窯業原料學 李鍾根
  2. Am. Creram. Soc. Bull v.43 no.6 Solid State Reaction in High Talc Codies E.J. Plantz
  3. Am. Creram. Soc. Bull v.50 no.6 Anothite Ceramic Diel ectrics R.A. Gduler
  4. M.S. Thesis Application of Phase Diagrams to High Alumina Ceramics in the Cao-al₂ O₃-SiO₂System W.C. Simmos
  5. U.S. Pat. 2,568,237 Batch for Refractory Masses and Method of Consolidation F.E. Lathe
  6. Am. Creram. Soc v.43 no.4 Kinetic Approach to the Application of Phase diagrams for High Alumina Ceramics W.C. Simmons;Ralston Russel, Jr.
  7. Am. Creram. Soc. Bull v.45 no.8 A New Approach to Virtified Technical Ceramics J.K. Goodyear;Ralston Russel, Jr.
  8. Am. Creram. Soc. Bull v.48 no.8 BaO Glasses in High Alumina Ceramics R.J. Miller;Ralston Russel, Jr.
  9. Acta crystalline logr v.5 Hexagonal CaO-Al₂O₃2SiO₂ Gabrielle Donnay
  10. Am. J. Sci., Browen Two New crystalline phase of the Anorthite Composition CaO-Al₂O₃-2SiO₂ G.L. Davis;O.F. Tutrle
  11. U.S. Dept. Commerce National Bureau of Standards v.2 Crystal data Determinative Tables J.D.H. Donnay;Helen M. Ondik