A Study on the Development of Refractories for the Iron , Steel and Cement Manufacturing

제철, 제강 및 시멘트 제조용 내화물의 개발에 관한 연구

  • 김병호 (고려대학교 공과대학 재료공학과) ;
  • 변재동 (고려대학교, 공과대학 재료공학과)
  • Published : 1980.02.01

Abstract

The castable refractory, CaO.$2Al_2O_3$ is a useful alumina cement for iron, steel and cement for iron, steel and cement industries, however it is difficult to produce CaO.$2Al_2O_3$because of its high melting point(180$0^{\circ}C$) and narrow firing range. In this study, the coprecipitation method was used to produce CaO.$2Al_2O_3$ for lower temperature firing . This method involved the titration of mixed solution of calicum and aluminate which extracted from domestic kaolin with $NH4_OH$ solution under blowing $CO_2$ gas into the solution. The coprecipitate and its clacined products were analyzed by X-ray diffraction and DTA. The calcined products fired between 400 and 90$0^{\circ}C$ were amorphous, but at 100$0^{\circ}C$ the coprecipitate was converted into one compound, CaO$2Al_2O_3$. From those experimental results, it was found that we could synthesizze CaO.$2Al_2O_3$ at about 100$0^{\circ}C$ which is lower than conventional firing temperature by around 80$0^{\circ}C$. The refractoriness of this alumina cement was SK 34 and the compressive strength ( 1 day) was about 250kg/$\textrm{cm}^2$.

Keywords

References

  1. High-Alumina Cements and Concretes T.D. Robson
  2. 鐵鋼製銶 尹東錫;梁勳永
  3. セラミックス v.4 no.5 アルミナセメソトの現狀と將來 近藤連一
  4. アルミナセメソト v.14 杉浦孝三
  5. 本誌 v.15 no.4 明礬石을 利用한 알루미나시멘트의 製造 韓基成
  6. 本誌 v.16 no.3 明礬石을 利用한 알루미나시멘트의 製造(II) 韓基成;崔相旭;宋泰雄
  7. セラミックス v.12 no.5 共沈法によるセラミックス復合材料の合成 寶地戶;雄辛
  8. 日工化誌 no.6 ??土の??理による表?狀能の?化 田中浦
  9. セメソト技術年報 v.XVIII no.50 アルミソ?カルツウムの生成機樹 內川浩;津曲明;小池英樹
  10. Am. Ceram. Soc. v.Fig.231 Phase Diagrams for Ceramists E.M. Levin;C.R. Robbins;H.F. McMurdie
  11. 日窯協 v.88 no.4 Thermal Decomposition of Aluminium Hydroxide Prepared by NH₃ Gas-AlCl₃ Solution Reaction Mitsuhiro Takase;Toshiyuki Sata