Mineral and Chemical Changes in Silica Brick After Service in Arc-furnace Roofs

아-크로 천장 사용후의 규석벽돌의 광물 및 화학적 변화

  • Published : 1981.04.01

Abstract

Silica bricks had been in arc-furnace roofs of various sizes and steelmaking practices. The resulting materials were examined with reference to mineral and chemical changes. Silica bricks develope definite zones while in service. These zones represent a concentration gradient through the brick that results from the thermal gradient across the brick and from the furnace atmosphere. There are major brick losses by spalling as well as by melting of the hot-face surface in an iron-oxide rich liquid.

Keywords

References

  1. ELECTRIC FURNACE STEELMAKNG, Chapter 18 Physical Chemistry of Steelplant Refractories(2nd Edition) v.2 E.F. Osborn;A. Muan;C.E. Sims(ed.)
  2. J. Phys. Chem. v.58 The Stability of SiO Solid and Gas L. Brewer;R.K. Edward
  3. Phys. Chem. Solid v.2 Differential Thermal Analysis of the Si-SiO2 System Brewer, J.;F.T. Greene
  4. J. Chem. Phys. v.23 Mass Spectrometric Study of Gaseous Species in the Si-SiO, System Porter, R.F.; W.A. Chupka;M.G. Inghram
  5. U.S. Bur. Mines. Bull. no.542 Contributions to the Data on Theoretical Metallurgy. XII. Heats and Free Energies of Formation of Inorganic Oxides Coughlim, J.P.
  6. Thermochemistry for Steelmaking v.I Elliott, J.F.;M. Gleiser
  7. J. ISI v.202 Refractories for are furnace at Steel, Peech, and Tozer R. Duck;J.R. Lakin
  8. AIME Elec. Furn. Steel Conf. Proc v.10 Melting Practice and Refractories Performance in Basic Electric-are furnace M.P. Fedock
  9. REFRACTORIES for iron-and steelmaking v.85 no.7, 1965 K. Konopicky;Stahl Eisen;J.H. Chester
  10. Trans. J. Brit. Ceram. Soc. v.51 no.2 Low-Alumina Silica Bricks : V. Properties and Performance J. Mackenzie
  11. Trans. J. Brit. Ceram. Soc. v.64 no.2 Progress in refractories for Steelmaking J.R. Lakin
  12. Trans. AIME v.203 Phase Equilibria in the System FeO-Fe₂O₃-SiO₂ A. Muan
  13. Am. J. Sci. v.26 The Bystem CaO-FeO-SiO₂ N.L. Bowen;J.F. Schairer;E. Pusnjak
  14. J. Am. Ceram. Soc. v.38 The Orthosilicate-Iron Oxide Portion of the System CaO-"FeO"-SiO₂ W.C. Allen;R.B. Snow
  15. J. Am. Ceram. Soc. v.42 Phase Equilibria in the System CaO-Iron Oxide-SiO₂ in Air B. Phillips;A. Mean
  16. J. Am. Chem. Soc. v.63 Thermody-namic Properties of the Crystalline Forms of Silica M.A. Mosesman;K.S. Pitzer
  17. J. Am. Ceram. Soc. v.44 Conversion of Quartz to Tridymite S.B. Holmquist