Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Model Studies in Photosynthesis (I). Synthesis and Characterization of Some Novel Pyropheophorbide Derivatives

  • Lee, Eun (Department of Chemistry, College of Natural Science, Seoul National University) ;
  • Chang, Won-Ghil (Department of Chemistry, College of Natural Science, Seoul National University) ;
  • Park, Sang-Chul (Department of Chemistry, College of Natural Science, Seoul National University) ;
  • Park, Sang-Kyu (Department of Chemistry, College of Natural Science, Seoul National University) ;
  • Kim, Hong-Doo (Department of Chemistry, College of Natural Science, Seoul National University) ;
  • Lee, Jo-Woong (Department of Chemistry, College of Natural Science, Seoul National University)
  • Published : 19811200
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Abstract

2'-(9"-Anthracenecarbonyloxy)ethyl pyropheophorbide a, methyl 3a-(9'-anthracenecarbonyloxy)pyropheophorbide a, 2'-(4"-phenylbenzoyloxy)ethyl pyropheophorbide a, and methyl 3a-(4'-phenylbenzoyloxy)pyropheophorbide a were prepared from chlorophyll a and b. Nuclear magnetic resonance study showed that the sandwich conformation is more favorable in 2'-(9"-anthracenecarbonyloxy)ethyl pyropheophorbide a than it is in other compounds.

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References

  1. Bioenergetics of Photosynthesis Govindjee(ed.)
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  4. Photochem. Photobiol. v.32 G. Dirks;A. L. Moore;T. A. Moore;D. Gust
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  6. Nature v.290 R. V. Bensasson;E. J. Land;A. L. Moore;R. L. Crouch;G. Dirks;T. A. Moore;D. Gust
  7. The Chlorophylls L. P. Vernon(ed.);G. R. Seely(ed.)

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  1. Photodynamic Effect of Water Soluble Piperazinium and Imidazolium Salts of HPPH on A549 Cancer Cells vol.29, pp.12, 1981, https://doi.org/10.5012/bkcs.2008.29.12.2505