Effect of $V_2O_5$ and $H_3BO_3$ Additives on Sintering of Magnesium Oxide

Magnesia 소결에 미치는 $V_2O_5$$H_3BO_3$ 첨가의 영향

  • Published : 1983.03.01

Abstract

This experiment has been carried out for the purpose of investigating the effect of $V_2O_5$ and $H_3BO_3$ additives on sintering of magnesium oxide over the temperature range of 1300-150$0^{\circ}C$ MgO powder has been obtained by calcin-ing extra reagent grade magnesium carbonate(basic) at 90$0^{\circ}C$ for 30 minutes. The specimens were prepared by compression with pressure of 700Kg/cm2 then fired at 1300-150$0^{\circ}C$ for 0-5hrs. Sintering behaviour and microstructure of fired specimens were examined. Densification rates obeyed the equation D=K 1n t+C. The ratio of density in case of addition of $V_2O_5$ to theoretical density of pure periclase was 95-99% Activation energy of densification in case of $V_2O_5$ addition was 30.15 Kcal/mole. The range of average grain size in case of addition of $V_2O_5$ was 40-50$\mu\textrm{m}$. $H_3BO_3$ addtivie had not an effect on densification of MgO.

Keywords

References

  1. J. Am. Lithium Ceram. Soc. v.40 no.6 Effect of Some Lithium Com-pounds on Sintering of MgO L. M. ATIAS
  2. J. Soc. Chem. Ind. v.42 no.6 Effect of Titanium Dioxide on Sintering of Magnesite:1. Formation of Magne-sium Titanatc YASUO;TANAKA
  3. Tech-nical Report No.11, Atomic Energy Commission Contract Effect of Oxide Additions on Sintering of Magnesia J. W. NELSON;I. B. CUTLER
  4. J. Am. Ceram. Soc. v.42 no.9 Effect of Minor Additions on Sintering of MgO G. K. LAYDEN;M. C. McQUARRIE
  5. Ceramic Bulletin v.44 no.6 Sintering in Very Pure Magne-sium Oxide and Magnesium Oxide Containing Vanadium R. A. BROWN
  6. 日本窯業協會誌 v.85 no.1 Etching Figures of Magnesia Specimens K. HAMANO;H. KAMIZONO
  7. 日本窯業協會誌 v.90 no.10 Effect of Silicon Diphosphate Addition on Sintering of Magnesium Oxid M. KINOSHITA;K. ITATANI
  8. Ceram. Abstr. Reactivity of Solids-Proceedings of the 4th In-ternational Symposium P. E. D. Morgan;A. J. Welcb
  9. 日本窯業協會誌 v.87 K. HAMANO;K. MUROYAMA;Z. NAKAGA-WA;K. SAITO
  10. J. Am. Ceram. Soc. v.53 no.2 Densification Mechanisms in Hot-Pressing of Magnesia with a Fugitive Liquid P. E. Hart;R. B. Atkin;J. A. Pask
  11. J. Am. Ceram. Soc. v.54 no.4 Hot-Pressing of MgO with NaF R. W. Rice
  12. Refractories v.147 no.22 A review on corrosion of refractories due to attack by vapour of various kinds T. Hayash