Intercalation of Ca-montmorillonite with Decylammonium Ion and n-Alcanol

Decylammonium 이온과 n-Alcanol 분자에 의한 Ca-montmorillonite의 Intercalation

  • 최진호 (서울대학교 자연과학대학 화학과) ;
  • 김창은 (연세대학교 공과대학 요업공학과) ;
  • 형경우 (연세대학교 공과대학 요업공학과)
  • Published : 1983.03.01

Abstract

The determination of charge density and charge distribution in montmorillonite are discussed. The method is based on cation exchange of the inorganic interlayer cations against decylammonium ion and molecular intercalation of n-alcanol. The results obtained from Yougil-bentonite show that charge density of 0.37 per unit formula and cation exchange capacity of 102.5 meq/100g.

Keywords

References

  1. J. Chem. Phys v.21 no.4 Adsorption studies on clay minerals. Ⅱ A for-mulation of the thermodynamics of exchange adsorption George L. Gaines, Jr.;Henry C. Thomas
  2. J. Am. Chem. Soc. v.74 no.6 Adsorption of water vapor by montmorillonite.Ⅰ. Heat of desorption and application BET theory R. W. Mooney;A. G. Keenan;L. A. Wood
  3. Z. Naturforschg. 24b Zur van der Waals Wechselwirkung in n-Dodecylammonium-Schicht-silicaten G. Lagaly;Armin Weiss
  4. Am. Mineralogist v.49 Complexes of Ca-montmorillonite with primary monohydric alcohols G. W. Brindley;Satyabrata Ray
  5. Can. J. Chem. v.60 Ther-mochemistry of ion exchange and particle interac-tion in clay suspensions Laurier L. Schramm;Jan C. T. Kwak
  6. Can. J. Chem. v.59 Clay chemistry: Investigation of thermodynamics of ion exchange reactions by titration calorimetry Gavin J. Ewin;Brian P. Erno;Loren G. Hepler
  7. J. Phys. Chem v.72 no.12 The swelling of alkylammonium montmorillonites W. H. Slabaugh;P. Anne Hiltner
  8. Am. Mineralogist v.50 Com-plexes of natural and synthetic Ca-montmorilloni-tes with fatty acids G. W. Brindley;William F. Moll;Jr
  9. Soils and Fernlizers v.28 no.5 Interaction between clays and organic compound in soils. Mechanisms of interaction between clays and defined organic compounds D. J. Greenland
  10. Intern. Clay Confer. Determination of the layer charge in mica type layer silicates G. Lagaly; A. Weiss
  11. in publication
  12. An introduction to clay colloid chemistry(2nd Ed.) H. van Olphen
  13. Clays and Clay Minerals(13th Conf) Infrared studies of the hy-droxyl groups in intercalated kaolinite complexes Robert L. Ledoux
  14. Clay and Clay Minerals(9th Conf.) Dehydration and rehydration studies of clay minerals by infrared absorption spectra Serratosa;J. M.
  15. J. Phys. Chem. v.67 Interaction between amm-ouia and the expanding lattice of montmorillonite and vermiculite M. M. Mortland(et al.)
  16. J. Phys. Chem. v.74 no.11 Hydrogen bonding in primary alkylammonium-vermiculite complex R. H. Laby; G. F. Walker
  17. Kolloid Z. Z. Poly-mere v.216 Ein einfaches verfa-hren zur Abschaetzung der Schichtladung quell-ungsfaehiger Schichtsilicate Armin Weiss;G. Lagaly
  18. Angew. Chem. Int. Ed. v.15 Kink-Block and Gauche-Block struc-ture of bimolecular films G. Lagaly