지리산산(智異山産) 침엽수재(針葉樹材) AcBr Lignin의 UV Spectra에 대(對)하여

On the UV Spectra of AcBr Lignins from Softwoods grown in Mt. Jiri

지리산산(智異山産) 침엽수재(針葉樹材) 10개(個) 수종(樹種)에 대(對)한 AcBr lignin의 UV spectrum을 조사(調査)하여 본 바 각(各) 수종(樹種) 모두 spectrum curve의 정점(頂點)은 249nm(Max. peak), 267-268nm(Shallow min. peak), 280nm(Lower max. peak)에 있었으며 Bjorkman lignin이나 lignin sulfonic acid 등(等)의 UV spectrum 상(上)에서 볼 수 있는 견(肩)은 AcBr lignin의 spectrum curve 상(上)에서는 볼 수 없었으며 각(各) 정점(頂點)의 10개(個) 수종(樹種) 평균(平均) 흡광도(吸光度)와 흡광계수(吸光係數)는 249nm에 각각(各各) $0.367{\pm}0.0015$, $24.56{\pm}0.0535$, 267-268nm에서 $0.278{\pm}0.0016$, $18.50{\pm}0.0569$ 였고 280nm에서는 $0.306{\pm}0.0016$, $20.42{\pm}0.0627$ 이었다.

The ultraviolet absorption spectra of AcBr lignin (Acetyl Bromide lignin) from 10 species grown in Mt. Jiri were determined. There were 3 peak positions, at 249nm (max peak), at 267-268 nm (shallow min. peak) and at 280 nm (lower max. peak). The Bjorkman lignin and lignin sulfonic acid spectra had shoulders, but the AcBr lignin had not them. Average absorbances and absorptivities of the AcBr lignins at peak positions were $0.367{\pm}0.0015$, $24.56{\pm}0.0535$, at 249 nm, $0.278{\pm}0.0016$, $18.50{\pm}0.0569$, at 267-268 nm and $0.306{\pm}0.0016$, $20.42{\pm}0.0627$ at 280 nm, respectively.