Effect of $ SO_3$ on Calciumsilicate Formation(II)

Calciumsilicate의 생성반응에 미치는$ SO_3$의 영향(II)

  • 임은극 (서울대학교 대학원 무기재료공학과) ;
  • 박병철 (서울대학교 대학원 무기재료공학과)
  • Published : 1984.02.01

Abstract

In this study a comparative investigation for the effect of $K_2SO_4$ and $CaSO_4$ on the decomposition of $C_3S$ was made. When pure $C_3S$ which was synthesized in the laboratory was mixed with $K_2SO_4$ and oxides such as MgO $Al_2O_3$ and $Fe_2O_3$ and then reburned at the temperature range between 135$0^{\circ}C$ and 145$0^{\circ}C$ no decompo-sition occurred, But when $CaSO_4$ and $Fe_2O_3$ were added to $C_3S$ and then reburned at below 130$0^{\circ}C$ $C_3S$ was partly decomposed to $C_2S$and CaO composing $2C_2S$.$CaSO_4$ When $CaSO_4$ and $Al_2O_3$were added $C_3S$ was entirely decomposed to $C_2S$ and CaO at 1300~140$0^{\circ}C$ but it was not decomposed at 145$0^{\circ}C$.

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References

  1. I. Korean. Ceram. Soc. v.20 no.4 Calciumsilicate의 生成反應에 미치는 SO₃의 影響(Ⅰ) 林應極;朴炳哲
  2. Trans. J. Brit. Ceram. Soc. v.67 no.10 Studies of Role of Calcium Sulphate in the Manufacture of Portland Cement Clinker Gutt, W.;Smith, M.A.
  3. Cem. Technol. v.2 no.143151 Studies of Sulphates in Portland Cement Clinker Gutt, W.(et.);Smith, M.A.
  4. Cem. Concr. Res. v.7 The Thermal Decomposition of Ca₃SiO5 at Temperatures below 1250℃, 1, pure C₃S and Influence of excess CaO or Ca₂SiO₄ Mohan, K.;Glasser, F.P.
  5. Cem. Concr. Res v.7 The Thermal Decomposition of Ca₃$SiO_5$at Temperature below 1250℃ Ⅱ The Influence of Mg, Fe, Al and Na Oxides on the Decomposition Mohan, K.;Glasser, F.P.
  6. Zem-Kalk-Gips v.23 no.12 Campounds Containing Carbonate and Sulphate in Cement Manufacture Scholze, H.;Hildebrant U
  7. Tr Leningr Tekhnol Inst im Lonsoveta v.56 no.93 Study on the Stable Phases of Calcium Silicates Okorokov, S.D.;Golynko-Vol'fson, S.L.;Korneev V.I.