Preparation of Submicron Barium Titanate Powders.

초미립 $BaTiO_3$의 합성

  • 안영필 (한양대학교 무기재료공학과) ;
  • 김복희 (한양대학교 무기재료공학과) ;
  • 황재석 (한양대학교 무기재료공학과) ;
  • 유경섭 (경기공업개방대학 화학공학과)
  • Published : 1984.03.01

Abstract

Barium titanate powder was made by firing the complex hydroxide which had been synthesized with chemical wet process by the medium of $H_2O_2$. This experiment was done as following A mixed solution of $BaCl_2$, $TiCl_4$ and $H_2O_2$ with 1:1:10 mol ratio was prepared. Ammonium hydroxide was added into the mixed solution. In the range of pH 8-10 $BaTiO_3$ complex hydroxide was obtained and treated at room temperature 11$0^{\circ}C$, 20$0^{\circ}C$, 40$0^{\circ}C$ and $600^{\circ}C$. The results obtaiined from this experiment were as follows. At room temperature $BaTiO_3$ complex hydroxide was amorphous. Above 10$0^{\circ}C$ crystalline $BaTiO_3$ was obtained and particle size of $BaTiO_3$ was increased with elevated temperature. So the particle size of BaTiO3 could be controlled by the firing temperature. After treating $BaTiO_3$ complex hydroxide at 10$0^{\circ}C$ the average particle size of $BaTiO_3$ was 0.22$\mu\textrm{m}$.

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References

  1. IVe Symposium European de Metallurgic des prodres Grenoble(France), 13-16th v.166 M. Paulus
  2. Materials Science Research v.11 M. Paulus
  3. セラミックス v.5 no.11 ェレクトロセラミック用紛未の化學的合成 佐佐木宏
  4. セラミックス v.16 no.11 セラミックスの製造プロセス 田岐潤三;尾岐義治;水谷惟恭
  5. セラミック誘電體工學 岡崎淸
  6. J. Res. N.B.S. v.56 no.2677 W.S. Clabaugh;E.M. Swiggard;R. Gilchrist
  7. J. Amer. ceram. Soc. v.52 no.523 K.S. Mazdiyashi;R.T. Dolloff;J.S. Smith II
  8. J. Ceram. Bull. v.49 no.990 B.J. Mulder
  9. Ceramic Bulletuin v.1236 Preparation of Stoichiometric Barium Titanyl Oxalate Tetrahydrate Katsuya Kudaka;Kiyokata Iizumi
  10. チタソ고の製造方法 村田充弘
  11. Phys. Rev. v.126 no.5 Far-Infrared Dielectric Dispersion in BaTiO₃, SrTiO₃, and TiO₂ W.G. Spizer;R.C. Miller;D.A. Kleinman;L.E. Howarth
  12. Phys. Rev. v.105 no.6 Infrared-Absorption Studies on Barium Titanate and Related Materials J.T. Last