A Study on Sintering and Mechanical Properties of $Si_3N_4$

질화규소의 소결 및 기계적 성질에 관한 연구

  • 이회동 (한국과학기술원 정밀요업재료연구실) ;
  • 이준근 (한국과학기술원 정밀요업재료연구실)
  • Published : 1984.04.01

Abstract

This study has been carried out to sinter silicon nitride with additives and to show the effect of surface finishments on its strength and Weibull modulus which are two most important factors for its applications into structural ceramics. Silicon nitride was sintered with the additions of $Al_2O_3$ and $Y_2O_3$ under pressureless cond-ition. The optimum properties were obtained by sintering at 1, 75$0^{\circ}C$ for 3hrs under $N_2$ atmosphere and the strength showed 6, 500kg/$cm^2$ at room temperature and 3, 300kg/$cm^2$ at 120$0^{\circ}C$. The effects of surface treatment on the strength of sintered $Si_3N_4$ were studied and the results showed that fine surface treatment increased the strength by up to 50% The Weibull analysis showed that its modulus was increased with increasing fineness of surface finishments. It was concluded that the mechanical properties of sintered silicon nitride could be improved by fine surface grinding which implied the brittle-fracture nature of sintered silicon nitride.

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References

  1. J. Mater, Sci. v.10 no.71 Pressureless Sintering of Si₃N₄ G.R. Terwilliger;F.F. Lange
  2. Proceedings of the Workshop on Ceramics for Advnced Heat Engine, Orlando,Fla K.J. Rowclifie;P.J. Jorgensen
  3. Proc. of International Symposium of Factors in Densification and Sintering of Oxide and Non-oxide Ceramics Microstructural Development;Densification During Sintering of Si₃N₄ Akigiko Tsuge;katsutoshi komeya;Hiroshi Inoue;Hachiro Hashimoto;Micgiyasu Komatsu
  4. International Metals Reviews v.247 no.1 Silcon nitride,polyphase systems:fabrication,microstructure and propertics F.F. Lange
  5. Technical Reports.Control#No.0014-14-C-0284 no.9 Dense Si₃N₄:Interrelation between Phase Equilibria,Microstructure and Mechanical Properties F.F. Lange
  6. J. App. Mech v.18 no.293 A Statistical Distribution Function of wide Applicability W. Weibull
  7. J. Kor. Ceram. Soc. v.21 no.1;62 The effects of Surface Finish and Grain Size on the Strength of Sintered SiC Young-Hyuk You;Young-Wook Kim;June-Gunn Lee;Chong-Hee Kim
  8. J. Am. Ceram, Soc. v.47 no.11 Influence of Surface Condition on the Stregth of Polycrystalline MgO W.B. Harrison