Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Anomalies of Supercooled Water

  • Yoon, Byoung-Jip (Department of Chemistry Korea Advanced Institute of Science and Technology) ;
  • Jhon, Mu-Shik (Department of Chemistry Korea Advanced Institute of Science and Technology)
  • Published : 1984.04.20
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Abstract

The anomalous behaviors of supercooled water are explained by using a two-solid-like structure model in which an equilibrium is assumed between open structures and closed structures. Besides these structures, small fraction of monomer exists in liquid water. The anomalies of liquid water are classified into two groups: structural and energetic. The structural anomalies appear in enlarged fashions in a supercooled state where the free volume is small.

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