Bulletin of the Korean Chemical Society

  • 제5권2호
  • /
  • Pages.82-86
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  • 1984
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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The Anomalies of Supercooled Water

  • Yoon, Byoung-Jip (Department of Chemistry Korea Advanced Institute of Science and Technology) ;
  • Jhon, Mu-Shik (Department of Chemistry Korea Advanced Institute of Science and Technology)
  • 발행 : 1984.04.20
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초록

The anomalous behaviors of supercooled water are explained by using a two-solid-like structure model in which an equilibrium is assumed between open structures and closed structures. Besides these structures, small fraction of monomer exists in liquid water. The anomalies of liquid water are classified into two groups: structural and energetic. The structural anomalies appear in enlarged fashions in a supercooled state where the free volume is small.

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참고문헌

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피인용 문헌

  1. Vibrational quantum correction for the Lennard‐Jones fluid: A formalism of effective intermolecular potentials depending on mass and temperature vol.92, pp.6, 1984, https://doi.org/10.1063/1.457833