Effect of Organic Admixture(Calcium Lignosulfonate) on the Early Hydration Process of Portland Cement(III)

시멘트 초기수화과정에 대한 유기혼화제의 영향(III)

  • 문정연 (한양대학교 무기재료공학과) ;
  • 최상홀 (한양대학교 무기재료공학과)
  • Published : 1985.01.01

Abstract

The effect of calcium lignosulfonate (CLS) on the early hydration characteristics for clinker minerals was investigated. In the presence of CLS and unsufficient gypsum The hydration of $C_3$A lowered CLS adsorption to form ettrin-gite and the residual CLS in the liquid phase accelerated the solubility of C4AF hydration. As the result unreacted $Fe^{3+}$ in the liquid phase would be precipitated gelatinously on $C_3$ hydrates and the hydration of $C_3$ could be retarded. But by addition of optimum gypsum into the cement with CLS the presence of $Fe^{3+}$ in the liquid phase were lowered and $C_3$ hydration would be normallized.

Keywords

References

  1. Proc. 3rd Int. Symp. Chem. Cem. Oil Well Cements W.C. Hansen
  2. Amer. Soc. Test. Mater. Spec. Tech. Publ. v.266 Symposium of Effect of Water-Reducing Admixtures and Set Retarding Admixture on Properties of Concrete W.C. Hansen
  3. Semento Gijutsu Nempo v.13 Influence of Saccharites and Other Organic Additives on the Hydration of Portland Cement S. Suzuki;S. Nishi
  4. Proc. 4th. Int. Symp. Chem. Cem. v.Ⅱ Some Chemical Additions and Admixtures in Cement Paste and Concrete J.H. Taplin;H.E. Vivian
  5. Proc. 5th Int. Symp. Chem. Cem. v.Ⅳ Effect of Organic Compounds on the Hydration Reactions of Tricalcium Aluminate K.E. Daugherty;M.F. Rowaleuski
  6. Proc. 5th Int. Symp. Chem. Cem. v.Ⅱ The Influence of Sugars on the Hydration of Tricalcium Aluminate J.F. Young
  7. PCA Res. Bulletin 98 The Setting of Portland Cement A Review of Theory, Performance and Control H.H. Steinou
  8. セメント機術年報 v.27 凝結遲延濟 の分子構造ならぴにヒメントとの作用機構 山本泰彦
  9. Cem. Concr. Res. v.21 no.4 A Review of the Mechanism of Set-Retardation in Portland Cement Pastes containing Organic Admixtures J.F. Young
  10. J. Kor. Ceram. Soc. v.21 Effect of Organic Admixture (Calcium Lignosulfonate) on the Early Hydration Process of Portland Cement (Ⅰ) J.Y. Moon;S.H. Choi
  11. J. Kor. Ceram. Soc. v.21 Effect of Organic Admixture (Calcium Lignosulfonate) on the Early Hydration Process of Portland Cement (Ⅱ) J.Y. Moon;S.H. Choi