Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

MULTIPHONON ABSORPTION IN $As_2S_3$ AND $GeS_{2.1}$ GLASSES

$As_2S_3$ 유리와 $GeS_{2.1}$ 유리의 Multiphonon 영역에서의 흡수

  • ;
  • C. T,. Moynihan
  • 마동성 (경북대학교 전자공학과) ;
  • Published : 1985.02.01
Download PDF
⟨ Previous Next ⟩

Abstract

2.5~40$mu extrm{m}$ 영역에서 $As_2S_3$ 및 $GeS_{2.1}$ 유리의 적외선흡수에 관하여 연구했다. Lucovsky와 그의 연구팀이 제창훈 분자 모델에 의하면 8-20$\mu\textrm{m}$ 영역에서 위의 유리물질의 multiphonon 흡수대는 고립된 각 분자의 기본진동대의 overtone 및 combination과 같다. Lucovsky와 Galeener는 이이론에 입각하여 network 구조를 갖는 유리가 적외선 및 라만 스펙트럼에서 나타나는 multiphonon combination 과 overtone 진동수를 예언하는 실험적 선택룰을 제안했다 우리가 얻은 As2S3 및 GeS2.1 유리의 적외선 스펙트럼은 이 유리에 대해 적용한 위의 실험법칙과 잘 일치한다.

Keywords

References

  1. J. Non-Cryst. Solids A molecular model for the vibrational modes in chalcogenide glasses G. Lucovsky;R.M. Martin
  2. Phys. Rev. B. v.6 no.4 Optic modes in amorphous $As_2S_3$ and $As_2Se_3$ G. Lucovsky
  3. Phys. Rev. B. v.9 no.4 Study of the optic modes of $Ge_{0.30}S_{0.70}$ glass by infrared and Raman spectroscopy G. Lucovsky;J.P. deNeufville;F.L. Galeener
  4. Phys. Rev. B. v.10 no.12 Structural interpretation of the infrared and Raman spectra of glasses in the alloy system G. Lucovsky;F.L. Galeener;R. Keezer;R.H. Geil;H.A. Six
  5. J. Non-Cryst. Solids v.5 no.286 Properties and structure of glasses in the system As-S Shoji Tsuchiahashi;Yoji Kawamoto
  6. 6th Int. Conf. on Amorphous and Liquid Semiconductors Infrared studies of amorphous semiconductors G. Lucovsky;F.L. Galeener
  7. 6th Int. Conf. on Amorphous and Amorphous and Liquid Semiconductors Infrared studies of amorphous semiconductors F.L. Galeener;G. Lucovsky
  8. Phys. Letters A. v.94A no.5 Molecular vibrationin Sn(Pb)GeS₃and GeS₂ Z.V. Popovic
  9. J. Non-Cryst. Solids v.37 no.2 Bulk and impuity infrared absorption in $0.5As_2Se_3-0.5GeSe_2$ glass D.S. Ma;P.S. Danielson;C.T. Moynihan
  10. Solid State Commun v.15 no.5 Multiphonon absorption in $As_2S_3-As_2Se_3$ glasses M.S. Maklad;R.K. Mohr;R.E. Howard;P.B. Macedo;C.T. Moynihan
  11. J. Non-Cryst. Solids v.17 no.369 Intrinsic and impuity infrared absorption in $As_2Se_3$ glasses C.T. Moynihan;P.B. Macedo;M.S. Maklad;R.K. Mohr;R.E. Howard
  12. Phys. Chem. Glasses v.5 no.3 Preparation of glasses transmitting in the infrared between 8 and 15 microns J.A. Savage;S. Nielsen
  13. J. Non-Cryst. Solids v.20 no.1 Structure and physical properties of the glassy arsenic-sulfur-germanium($As_2S_3Ge_{X}$)system R. Andreichin;M. Nikiforova;E. Skordeva;L. Yurukova;R. Grigorovici;R. Manaila;M. Popescu;A. Vancu
  14. J. Am. Ceram. Soc. v.52 no.11 Glass-forming regions and structure of glasses in the system Ge-S Yoji Kawamoto;Shoji Tsuchiahashi
  15. J. Am. Ceram. Soc. v.54 no.3 Properties and structure of glasses in the system Ge-S Yoji Kawamoto;Shoji Tsuchiahashi
  16. Solid State Commun. v.17 no.12 Coordination dependent vibrational properties of amorphous semiconductor alloys G. Lucovsky;R.J. Nemanich;S.A. Solin;R.C. Kcezer
  17. Infrared Physies v.5 no.195 Chalcogenide glasses transmitting in the infrared between 1 and 20μ-a state of the art review J.A. Savage;S. Nielsen
  18. J. Non-Cryst. Solids v.51 no.317 Optical properties of vitreous GeS₂ B. Voigt;M. Wolf
  19. Solid State Commun. v.49 no.9 Qualitative DS calorimetry of some sulfur rich glasses L. Tichy;N. Rysava;A. Triska;H. Ticha;J. Klikorka