Infrared Absorption in $XAs_2S_3-(1-X)GeS_2$ Glassses in Multiphonon Region

$XAs_2S_3-(1-X)GeS_2$ 유리의 Multiphonon 영역에서의 적외선 흡수

  • 마동성 (경북대학교 전자공학과)
  • Published : 1985.03.01

Abstract

2.5~40$mu extrm{m}$ 영역에서 $XAs_2S_3-(1-X)GeS_2$ 유리의 적외선 흡수에 관하여 연구했다/ Lucovsky와 그의 연구팀이 제창한 ""분자모델""에 의하면 $8-20\mu\textrm{m}$ 영역에서 위의 유리물질의 multiphonon 흡수대는 고립된 각 분자의 기본진동대의 overtone 및 combination 과 같다. 그러므로 multiphonon 흡수영역에서 AsY3 와 GeY3의 기본진동수를 모두 가지고 있는 combination 대는 관찰되지 않고 또한 혼합된 $XAs_2S_3-(1-X)GeS_2$ 유리의 흡수계수는 순수한 $As_2Y_3$$GeY_2$ 유리의 흡수계수를 더한 것으로 표현된다. 실험에서 얻은 흡수계수는 이 분자모델로부터 예상되는 값과 잘 일치한다.값과 잘 일치한다.

Keywords

References

  1. J. Non-Cryst. Solids. v.8-10 A molccular model for the vibrational modes in chalcogenide glasses G. Lucovsky;R.M. Martin
  2. Phys. Rev. B. v.6 no.4 Optic modes in amorphous As₂S₃and As₂Se₃ G. Lucovsky
  3. Phys. Rev. B. v.9 no.4 Study of the optic modes of $Ge_{0.30}$$S_{0.70}$ glass by infrared and Raman spectroscopy G. Lucovsky;J.P. deNeufville;F.L. Galeener
  4. Phys. Rev. B. v.10 no.12 Structural interpretation of the infrared and Raman spectra of glasses in the alloy system G. Lucovsky;F.L. Galeener;R.H. Geil;H.A. Six
  5. J. Non-Cryst. Solids v.5 Properties and structure of glasses in the system AsS Shoji Tsuchiahashi;Yoji Kawamoto
  6. Paper presented at the 6th Int. Conf. in Amorphous and Liquid Semiconductors Infrared studies of amorphous semiconductors G. Lucovsky;F.L. Galeener
  7. Paper presented at 6th Int. Conf. on Amorphous and Liquid Semiconductors Infrared studies of amorphous semiconductors F.L. Galeener;G. Lucovky
  8. Phys. Letters A v.94(A) no.5 Molecular vibration in Sn(Pb)GeS₃and GeS₂ Z.V. Popovic
  9. Solid State Commun. v.15 no.5 Multiptiphonon absorption in As₂S₃As₂Se₃glasses M.S. Maklad;R.K. Mohr;R.E. Howard;P.B. Macedo;C.T. Moynihan
  10. Optical properties of highly transparent solids R.E. Howard;P.S. Daniclson;Maklad;R.K. Mohr;P.B. Macedo;C.T. Moynihan;S.S. Mitra(ed.);B. Bendow(ed.)
  11. J. Non-Cryst. Solids v.37 no.2 Bulk and impurity infrared absorption in 0.5 As₂Se₃-0.5 GeSe₂glass D.S. Ma;P.S. Danielson;C.T. Moynihan
  12. Journal of the Korean Ceramic Society Multiphonon absorption in As₂S₃and $GeS_{2.1}$ glasses Dong Sung Ma;C.T. Moymhan
  13. J. Non-Cryst. Solids v.51 Optical properties of vitreous GeS₂ B. Voigt;M. Wolf
  14. Solid State Commun. v.49 no.9 Qualitative DS calorimtry of some sulfur rich glasses L. Tichy;N. Rysava;A, Triska;H. Ticha;J. Klikorka
  15. Solid State Commun. v.17 no.12 Coordination dependent vibrational properties of amorphous semiconductor alloys G. Lucovsky;R.J. Nemanich;S.A. Solin;R.C. Kcezer
  16. Phys. Stat. Sol. (b) v.94 Infrared reflection and Raman scattering studies of vibrational properties and structure of As₂S₃$Go_x$ glasses M. Giehler;W. Pilz