Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Concentration Dependence of the $\nu_1$ Isotropic Raman Band of Nitromethane in Chloroform-d, Pyridine-d$_5$, 1,3,5-Trifluorobenzene, and Hexafluorobenzene

  • Choe, Joong-Chul (Molecular Structure Group, Department of Chemistry, Seoul National University) ;
  • Kim, Myung-Soo (Molecular Structure Group, Department of Chemistry, Seoul National University)
  • Published : 1986.08.20
Download PDF
⟨ Previous Next ⟩

Abstract

Concentration dependences of the isotropic Raman band width and the peak position for the ${\nu}_1$ (C-H stretching) mode of nitromethane in chloroform-d, pyridine-$d_5$, 1,3,5-trifluorobenzene, and hexafluorobenzene have been investigated. For all solutions, the experimental concentration dependences have been well described by the concentration fluctuation model of Knapp and Fischer when appropriate values for the effective numbers (N) of nearest neighbors were used. For the $CH_3NO_2/C_6F_6$ solution, an abnormally small value (2) of N indicates strong intermolecular interaction.

Keywords

References

  1. Chem. Phys. v.100 H. Abramczyk;W. Reimschussel
  2. J. Raman Spectrosc. v.16 K. Fujita;T. Fukuda;M. Kimura
  3. J. Chem. Phys. v.81 E.W. Knapp
  4. J. Phys. Chem. v.87 D.W. Oxtoby
  5. Rev. Mod. Phys. v.50 A. Laubereau;W. Kaiser
  6. Chem. Phys. Lett. v.82 A. Fendt;S.F. Fischer;W. Kaiser
  7. J. Chem. Phys. v.66 J. Schroeder;V.H. Schieman;P.T. Sharko;J. Jonas
  8. J. Chem. Phys. v.67 K. Tanabe;J. Jonas
  9. Bull. Korean Chem. Soc. v.7 J.C. Choe;M.S. Kim
  10. Chem. Phys. Lett. v.100 H. Abramczyk
  11. Chem. Phys. Lett. v.35 S.F. Fischer;A. Laubereau
  12. Mol. Phys. v.51 H.J. Bohm;R.M. Lynden-Bell;P.A. Madden;I.R. McDonald
  13. Chem. Phys. v.21 G. Doge;R. Arndt;A. Khuen
  14. Opt. Spectrosc. v.35 A.F. Bondarev;A.I. Mardaeva
  15. J. Chem. Phys. v.76 E.W. Knapp;S.F. Fischer
  16. J. Chem. Phys. v.81 B.P. Asthana;W. Kiefer;E.W. Knapp
  17. J. Korean Chem. Soc. v.20 M.S. Kim;K.J. Shin
  18. Spectrochim. Acta. v.30A K. Tanabe;J. Hiraishi
  19. Adv. Mag. Reson. v.3 R.G. Gordon
  20. Bull. Chem. Soc. Jpn. v.49 T. Fujiyama;M. Kakimoto;T. Suzuki
  21. Z. Naturforsch. Teil v.A35 G. Doge;R. Arndt;H. Buhl;G. Bettermann
  22. J. Chem. Educ. v.47 J.T. Edward
  23. Farad. Discuss. Chem. Soc. v.66 N.M.D. Brown;J.F. Maguire;F.L. Swinton
  24. Trans. Farad. Soc. v.64 W.J. Graw;F.L. Swinton
  25. Bull. Korean Chem. Soc. v.5 H.J. Hwang;M.S. Kim
  26. Master Thesis, Seoul National University H.J. Hwang
  27. J. Raman Spectrosc. v.12 K. Tanabe;J. Hiraishi
  28. Spectrochim. Acta v.36A R.T. Bailey;R.U. Ferri
  29. J. Chem. Soc. Chem. Commun. N.M.D. Brown;F.L. Swinton

Cited by

  1. Molecular dynamics and vibrational relaxations in liquid nitromethane. vol.75, pp.5, 1986, https://doi.org/10.1080/00268979200100831
  2. Quasi-Elastic Light Scattering by Hydrodynamic Modes in Small Polar Molecules. Nitromethane vol.204, pp.1, 1986, https://doi.org/10.1524/zpch.1998.204.part_1_2.235