Crystal Growth of Mn-Zn Ferrite form High-Temperature Solutions

융제법에 의한 Mn-Zn Ferrite 단결정성장에 관한 연구

  • 이성국 (한양대학교 무기재료공학과) ;
  • 오근호 (한양대학교 무기재료공학과) ;
  • 강원호 (삼성코닝 연구소)
  • Published : 1987.05.01

Abstract

Single crystals of Mn-Zn Ferrite were grown by slow cooling method using Na2B4O7 as flux agent. The effects of flux content and cooling rate on the types of crystals, and the relation between supersaturation and growth mechanism were studied. As a result, the types of grown crystals occurred as plate, hopper and octahedral crystals. The occurrence of these crystal types was dependent on flux content. The habit was found to correlate with the growth rate and supersaturation. The lateral growth of a dendritic crystal is related to the twin layer. The growth of crystals from borax melts mainly occurred by the layer-spreading growth following corner and edge nucleation caused by high supersaturation in the melt. Especially, the plate crystals were produced on top of the melts. The hopper and octahedral crystals occurred at lower supersaturation than the plate crystals.

Keywords

References

  1. J. Chem. Phys. v.20 no.990 The Growing of Single crystals of Magnetite J. Smiltens
  2. Proceedings of Int. Conf. on Ferrites Crystal Growth and Application of Manganese Zinc Ferrite Single Crystals in Japan M. Sugimoto
  3. Proceedings of Int. Conf. on Ferrites Variation of Composition in Mn-Zn Ferrite Crystals Grown by the Bridgman Method T. Sasaki;N. Watanabe;T. Nakajima
  4. Phys. Rev. v.81 Crystalline Magnetic Anisotropy in Zinc Manganess Ferrite J.K. Galt;W.A. Yager;J.P. Remeika;F.R. Merritt
  5. Growth of Crystals J. Kvapil;V.Jon;M. Vichr;N.N. Sheftal(ed.)
  6. Growth of Crystals v.2 V.A. Timofeeva;A.V.Zalesskii;Shubnikov(ed.);Sheftal(ed.)
  7. J. Crystal Growth v.19 Habit of Fe₂O₃Grown from $Na_2B_4O_7$ A.B. Chase;F.L. Morse,Jr
  8. J. Am. Ceram. Soc. v.44 no.3 Chracteristic Imperfections in Flux-Grown Crystals of Yttrium Iron Garnet R.A. Lefever;A.B. Chase;J.W. Torpy
  9. J. am. Ceram. Soc. v.45 no.7 Growth of Yttrium-Iron Garnet from Molten Bartium Borate R.C. Linares
  10. U.S. Patent v.2 no.848 Method of Making Single Crystal Ferrites J.P. Remeika
  11. Crystal Growth from High Temperature Solutions D. Elwell;H.J. Scheel
  12. J. Crystal Growth v.60 Surface Morphology of the(010) Faces of Potassium Hydrogen Phthalate Crystals W.J.P. Van Enckevort;L.A.M.J. Jetten
  13. J. Am. Ceram. Soc. v.51 no.9 Habit Changes and Growth Mechanisms of In₂O₃Grown from PbO-B₂O₃Melts A.B. Chase
  14. Growth of Crystals v.7 I.M. Skvortsov;N.N. Sheftal(ed.)
  15. Acta. Met. v.5 New Observations on the Structure of Germanium Dendrites E. Billing;P.J. Holmes
  16. Acta. Met v.8 On the Growth Germanium dendrites R.S. Wagner
  17. J. Electrochem. Soc. v.108 Germanium Dendrites Studies J.W. Faust, Jr.;H.F. John
  18. J. Am. Ceram. Soc. v.45 Analysis of Surface Features on Single Crystals of Synthetic Garnets R.A. Lefever;A.B. Chase
  19. J. Crystal Growth v.20 Surface Features on Flux-grown Refractory Oxide Crystals H.J. Scheel;D. Elwell
  20. J. Electrochem Soc. v.120 Stability and Stirring in Crystal Growth from High-Temperature Solutions H.J. Scheel;D. Elwell
  21. J. Am. Ceram. Soc. v.46 no.3 Suggested Mechanism for Formation of Hopper Crystals in Flux Systems R.A. Lefever;E.A. Giess