Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Aging Behavior and Electric Field Induced-Domain Stabilization in Cr2O3 Doped Pb(Zr0.525 Ti0.475)O3 System

Cr2O3첨가 Pb(Zr0.525 Ti0.475)O3계에서의 시효거동과 전계유도 Domain 안정화

  • 한이섭 (한국과학기술원 재료공학과) ;
  • 김호기 (한국과학기술원 재료공학과)
  • Published : 1987.05.01
Download PDF
⟨ Previous Next ⟩

Abstract

Cr2O3 doped Pb(Zr0.525 Ti0.475)O3 piezoelectric ceramics were prepared from reagent grade oxide mixture, PbO, ZrO2, TiO2 and Cr2O3. Piezoelectric and aging properties of specimens were measured for various additions of Cr2O3. Generally, it has been known that aging rate decreased with Cr2O3 addition by stabilizing the domain wall. But hysteresis loops showed that the domain destabilization was occurred at high electric field (larger than 10KV/cm). In smaller additions of Cr2O3 (0-0.2mol%), aging rate increased and microcracks were created with increasing poling filed due to increasing internal stress. In larger additions of Cr2O3(0.4∼0.6mol%), aging rate decreased with increasing poling field.

Keywords

References

  1. J. Am. Ceram. Soc. v.66 no.4 Sintering of PZT Ceramics: Ⅰ. Atmopshere Control A. I. Kingon;J. B. Clark
  2. Piezoelectric Ceramics B. Jaffe;J. R. Cook;H. Jaffe
  3. Ferro v.41 Effect on Impurity Doping in Lead Zirconate-Titanate Ceramics S. Takahashi
  4. Ferro v.40 Principles of Piezoelectric Ceramics for Mechanical Filters H. Thomann;W.Wersing
  5. J. Am. Ceram. Soc. v.52 no.4 Aging in Tetragonal Ferroelectric Barium Titanate R. C. Bradt;G. S. Ansell
  6. ibid v.55 no.1 Nature of Aging in Tetragonal Ferroelectric Barium Titanate G. H. Jonker
  7. Ceram. Bull. v.34 no.12 The Aging Effect in Brium Titanate M. C. McQurrie;W. R. Bussem
  8. J. Phys. Soc. Jpn. v.22 no.3 Mechanism of Aging in Polycrystalline BaTiO₃ S. Ikegami;I. Ueda
  9. J. Phys. Chem.Solids. v.47 no.5 The Nature of Domain Stabilization in Ferroelectric Perovskite P. V. Lambeck;G. H. Jonker
  10. Proc. IRE45 IRE Standards on Piezoelectric Crystals-The Piezoelectric Vibrator: Definition and Method of Measurement 1957
  11. Proc. IRE50 IRE Standards on Piezoelectric Crystals-Measurements of Piezoelectric Ceramics 1961
  12. J. Appl. Phys. v.49 no.8 Dielectric Losses in Ferroelectric Ceramics Produced by Domain-Wall Motion J. O. Gentner;P. Gerthsen;N.A. Schmidt;R.E. Sand
  13. ibid v.52 no.2 Correlation of Mechanical and Electrical Losses in Ferroelectric Ceramics P. Gerthsen;K. H. Hardtl;N. A. Schmidt
  14. Ceram. Inter. v.8 no.4 Electrical and Mechanical Losses in Ferroelectric Ceramics K. H. Hardtl
  15. J. Am. Ceram. Soc. v.53 no.7 Dielectric Aging in Tetragonal Solid Solutions of Cacium Titanate in Barium Titanate A. Cohen;R. C. Bradt;G. S. Ansell
  16. M. S. Thesis The Effect of Microstructure on the Electrical Properties in the Tetragonal Phase PZT H. T. Chung
  17. J. Am. Ceram. Soc. v.66 no.5 Dielectric, Electromechanical, Optical and Mechanical Properties of Lanthanium Modified Lead Titanate Ceramics T. Yamamoto;H. Igarashi;K. Okazaki
  18. Jpn. J. Appl. Phys. v.6 no.11 Studies on Pb(Zr-Ti)O₃ Ceramics with Adition of Cr₂O₃ N. Uchida;T. Ikeda
  19. Commun. Am. Ceram. Soc. no.10 Influence of Microcracking and Slow Crack Growth on Planar Couling Cefficient S. S. Chiang;R. M. Fulrath;J. A. Pask