Effect of MgO Contents on Electrical Properties and Oxygen Sensing Characteristics in Co1-xMgxO Ceramics

Co1-xMgxO세라믹스의 MgO함량에 따른 전기적 성질 및 산소가스 감지특성

  • Published : 1989.01.01

Abstract

The effects of composition ratios and sintering conditions in Co1-xMgxO ceramics on the sintering characteristics, electrical properties and oxygen sensing characteristics were investigated. In the same sintering conditions, porosity decreased with increase of MgO contents. The relationshiop of temperature and resistance in Co1-xMgxO ceramics showed NTC(negative temperature coefficient) characteristics at the temperature range from $700^{\circ}C$ to 1,10$0^{\circ}C$. In the case of pure CoO, however, the PTC(positive temperature coefficient) characteristics were shown over about 90$0^{\circ}C$. The electrical conductivity of Co1-xMgxO ceramics decreased proportionally with decrease of oxygen partial pressure at the range from 1 to 10-4(atm). Particularly, Co0.5Mg0.5O ceramics showed the highest sensitivity to oxygen gas.

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References

  1. J. Chem. Phys. v.44 no.4 Electrical Properties of Cobalt Monoxide Bertina Fisher;D.S.Tannhauser
  2. J. Am. Ceram. Soc. v.66 no.1 Electrical Conduction in $Co_{1-x}Mg_xO$ Kunihito Koumoto;Keiko Yamayoshi;Hirooaki Yananida
  3. Ber. Bunsenges Phys. Chem. v.77 no.6 Point Defects in Oxide Solid Solutions : I, Thermodynamics of Defects for the Solid $Solutions(Co_xMg_{1-x})O\;and\;(Co_xMg_{1-x})_2SiO_4$ V.G.Schwier;R.Dieckmann;H.Schmalzried
  4. Jpn, J. Appl. Phys. v.20 no.2 Decomposition Pressure of Co₃O₄Determined from Electrical Conductivity Measurements K.Koumoto;H.Yanagida
  5. Appl. Phys. Lett. v.26 no.209 Oxygen sensors using CoO Ceramics E.M.Logothetis;K.Park;A.H.Meitzler;K.R.Laud
  6. J. Electr. Chem. Soc. v.124 no.9 Oxygen Sensing with $Co_{1-x}Mg_xO$Ceramics K.Park;E.M.Logothetis
  7. Introduction to Ceramics(2nd Edition) W.D.Kingery;H.K.Bowen;D.R.Uhlmann
  8. Elements of Materials Science and Engineering(4th Edition) Laurence H.Van Vlack
  9. Engineering Circuit Analysis(3rd Edtion) W.H.Hayt;J.Kemmerly
  10. J. Am. Ceram. Soc. v.51 no.9 Sintering of ZnO : I, Densification and Grain Growth T.K.Gupta;R.L.Coble
  11. Ceramics Materials for Electronics Relva C.Vuchanan
  12. J. Kor. Ceram. Soc. v.24 no.3 석유증발법에 의한 Cobalt Oxide의 분말제조 윤상옥;정형진
  13. Sensors and Actuator v.12 Low Power Thick Films CO Gas Sensors D.D.Lee;B.K.Shon