고분해능 투과전자현미경 연구에 의한 ${\gamma}$-Al2O3의 상 전산모사

Compouter Image Simulation of ${\gamma}$-Al2O3 in High-Resolution Transimission Electron Microscopy

  • 이정용 (한국과학기술대학, 전자재료과) ;
  • ;
  • R. Gronsky (University of California, Berkeley)
  • 발행 : 1989.02.01

초록

Interpretation of high-resolution transmission electron microscopy images of defects and complex structures such as found in ceramics generally requires matching of the images with compound image simulations for reliable interpretation. A transmission electron microscopy study of the aluminum oxide was carried out at high-resolution, so that the crystal structure of the aluminum oxide could be modelled on an atomic level. In conjunction with computer simulation comparisons, the images reveal directly the atomic structure of the oxide. Results show that comparison between experimental high-resolution electron microscopy images and simulated images leads to a one to one correspondence of the image to the atomic model of the aluminum oxide. The aluminum atoms are disordered in the octahedral sites and the tetrahedral sites in the spinel aluminum oxide.

키워드

참고문헌

  1. 38th Ann. Proc. Electron Microscopy Soc. Arner. The U.S. Atom-Resolving Microscope Project R Gronsky;G W Baily(ed.)
  2. Experimental High-Resolution Electron Microscopy J.C.H. Spence
  3. Acta Cryst. v.A30 Numerical Evaluation of n-beam Wave Functions in Electron Scattering by the Multi-slice Method P Goodman;A.F. Moodie
  4. Electron Optical Systems Electron Image Simulation: A Complementary Processing Technique M A O'Keefe
  5. Optik v.1 Growth and Structure of Thin Oxide Layers on Aluminum G. Hass
  6. The Nature of Chemical Bond L. Pauling
  7. Proc. Brit. Ceram. Soc. v.69 no.85 Phase Transformations and Development of Microstructure in Boehmitederived Transition Aluminas S.J. Wilson
  8. Clay Min. Bull v.3 Dehydration of Gibbsite and the Structure of a Tetragonal r-Al₂O₃ H. Saalfeld
  9. J. Phys. Chem. v.71 Radial Electron Density Distribution Functions of Alumina Gels A.J. Leonard;F. Van Cauwelaert;J.J. Fripiat
  10. J. Solid State Chem. v.30 The Dehydration of Boehmite, r-AlOOH, to r-Al₂O₃ S.J. Wilson
  11. Acta Cryst. v.17 Study of Phase Transformations During Calcination of Aluminum Hydroxides by Selected Area Electron Diffraction B.C. Lippens;J.H. de Boer
  12. J. Phys. Chem. v.61 no.758 Vacancy Distribution and Bonding in Some Oxides of Spinel Structures K.P. Sinha;A P B. Sinha
  13. Treatise on Materials Science and Technology : Experimental Techniques v.19B High-Resolution Transmission Electron Microscopy R Gronsky
  14. Ph.D. Thesis Computer Simulation of High Resolution Transmission Electron Micrograph: Theory and Analysis R. Kilaas
  15. Acta Cryst. v.A24 no.390 Relativistic Hatree-Fock X-ray and Electron Scattering Factors P.A. Doyle;P.S. Turner
  16. Acta Cryst. v.10 The Scattering of Electrons by Atoms and Crystals. I. A New Theoretical Approach J.M. Cowley;A.F. Moodie