Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Nitrogenation of Coal Ash in the Presence of Carbon and Product Distributions of AlN, SiC and Si₃N₄

석탄회의 탄소가 첨가된 질화반응과 AlN, SiC 그리고 Si₃N₄의 생성분포

  • Published : 1990.08.01

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Abstract

A nitrogenation of coal ash in the presence of carbon was carried out to examine the effects of reaction temperature, reaction time and carbon composition on the formation of AlN, SiC and Si3N4. Decreasing the particle size increased the formation of AlN and its maximum composition in the product was obtaiend under 1450∼1500℃, 2 hours of reaction time and about 30% of carbon addition(on the basis of sample weight). Compositions of SiC and Si3N4 were distributed to the opposite so that SiC showed a higher composition compared with Si3N4 at a lower temperature, a shorter reaction time and a greater carbon addition.

석탄회의 탄소가 첨가된 질화반응시에 생성된 AIN, SiC 그리고 Si3N4 등의 생성물 분포를 반응온도, 시간 그리고 탄소의 첨가량에 따라 검토하였다. AIN의 조성은 시료입자가 작을수록 증가하였으며 반응온도 14500~1500℃와 약 2시간의 반응시간 그리고 약 30%의 탄소 첨가량 (시료무게 기준) 에서 최대값을 나타내었다. SiC와 Si3N4 조성변화는 서로 상반된 경향을 보였으며 반응온도가 낮고 반응시간이 작으며 그리고 탄소첨가량이 증가할 수록 SiC의 조성은 Si3N4 에 비하여 크게 나타났다.

Keywords

References

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