Thermodynamic Calculations of High Temperature Bubble Formation at SiC/$SiO_2$ Interface

SiC/$SiO_2$ 계면의 고온 기공발생에 관한 열역학적 계산

  • 이문희 (수원대학교 전자재료과) ;
  • 박종욱 (한국과학기술원 과학기술대학 전자재료과)
  • Published : 1990.04.01

Abstract

Numerous researchers have observed the bubble fromation at SiC/SiO2 interface from 130$0^{\circ}C$ to 1$700^{\circ}C$. According to thermodynamic calculation, the bubble could be formed from the microscopic impurities which result from the chemical vapor deposition of SiC. When C-impurity is present at the interface, it is calculated that the bubble is formed at 1511$^{\circ}C$ and when Si is present, the bubble is formed at 177$0^{\circ}C$. These results are very close to the prior observations, but the calculation can not explain the observation of bubble below 150$0^{\circ}C$.

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References

  1. J. Am. Ceram. Soc. v.67 no.1 D.W. Mieskowski;T.E. Mitchell;A.H. Heuer
  2. Oxidation Behavior of Chemically Vapor-deposited Silicon Carbide G.H. Schiroky
  3. Mass Transport Phenomena in Ceramics High Temperature Oxidation of Hot-pressed Silicon Carbide J.W. Hinze;W.C. Tripp;H.C. Graham;A.R. Cooper(ed.);A.H. Heuer(ed.)
  4. Proc. EMSA v.30 J.E. Doherty
  5. J. Am. Ceram. Soc. v.66 no.3 Angus I. Kingon;Leonard J. Lutz;P. Liaw;Robert F. Davis
  6. Recent Advances in Materials Research High Temperature Materials E. Fitzer;C.M. Srivastava(ed.)
  7. J. Am. Ceram. Soc. v.68 no.4 Gary S. Fischman;William T. Petuskey
  8. Thermodynamic Table JANAF
  9. J. Phys. Chem. v.67 E.T. Turkdogan;P. Grieveson;L.S. DArken