Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Glass Preparation of$ZrO_2$-$SiO_2$ System by the Sol-Gel Method

졸-겔법에 의한 $ZrO_2$-$SiO_2$계 유리 제조

  • 신대용 (강원대학교 재료공학과) ;
  • 한상목 (강원대학교 재료공학과) ;
  • 소명기 (강원대학교 재료공학과) ;
  • 이풍헌 (강원대학교 재료공학과)
  • Published : 1990.05.01
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Abstract

Glass in the ZrO2-SiO2 system containing up to 30mol% ZrO2 were prepared by heating the gel made from the mixed solutions of Zr(OC3H7)4 and partial hydrolysed Si(OC2H5)4. As a result, the monolith gel was made from the HCl and water content as 2.7$\times$10-3 and 8 molar ratio to alkoxide and drying temoperature as 4$0^{\circ}C$. Heating rate of dry gel maintained under 0.5$^{\circ}C$/min and heating at a temperature as 90$0^{\circ}C$ was found to be for making the transparent glass.

Keywords

References

  1. J. Non-Cryst Solids. v.73 Glass and Glass-Ceramics from Gel S. Sakka
  2. Adv. Ceram. v.3 A.H. Heuer;L.W. Hobbs
  3. J. Mater. Sci. Lett. v.4 Preparation of Amorphous Materials by Rapid Quenching of Melts in the System ZrO₂-SiO₂-Al₂O₃ M. Yoshimura;M. Kaneto;S. Somiya
  4. Am. Ceram. Soc. Bull. v.47 Chemical Durability of a Soda-Lime Glass with TiO₂,GeO₂, ZrO₂, and AlPo Partially Substituted for SiO₂ T. Baak;C.F. Rapp;H.T. Hartely;B.E. Wiens
  5. J. Mater. Sci. v.15 Preparation of Glass Fibers of the ZrO₂-SiO₂and Na₂O-ZrO₂-SiO₂System from Metal Alkoxides and Their Resistance to Alkaline Solution K. Kamiya;S. Sakka;Y. Tatemichi
  6. Yogyo-Kyokai-Shi. v.85 On the Properties of Noncrystalline Films M. Nogami;Y. Moriya
  7. 日本 窯業協會 學術 論文誌 v.96 no.9 Hydrolysis-Condensation of Zr-O-Si Alkoxide M. Nogami;K. Nagasaka
  8. J. Mater. Sci. v.12 Preparation of Glass and Ceramics from Metal Organic Compounds B.E. Yoldas
  9. J. Non-Cryst. Solids v.48 S. Sakka;K. Kamiya
  10. J. Non-Cryst. Solids. v.69 Glass Preparation of the ZrO₂-SiO₂ System by the Sol-Gel Process from Metal Alkoxide M. Nogami
  11. J. Chem. Phy. v.64 no.6 Water and it's Relation to Broken Bond Defects in Fused Silica R.H. Stolen;G.Z. Walarfen