Synthesis of $Fe_4N$ Powder and Its Magnetic Properties for Magnetic Recording

자기기록용 $Fe_4N$ 분말의 합성 및 자기특성

  • Published : 1991.02.01

Abstract

For determination the optimum manufacturing condition Fe4N powder for magnetic recording media, we have studied the following important conditions : the effect of particle size of metal powder on the nitridation, the condition of nitridation on the formation and magnetic properties of Fe4N, and stability of Fe4N powder against temperature and change on standing. The results can be summarized as : 1) Single phase Fe4N is formed at 50v/o of ammonia concentration during the nitridation reaction, 2) Single phase Fe4N is formed above 40$0^{\circ}C$, 15min regardless of the metal powder sizes, 3) Coercivity and saturation magnetization of Fe4N powder almost constant value until 20 day-passing from preparation date.

Keywords

References

  1. Ferrites Proceedings of the ICF3 The Development og Metal Powder for Magnetic Recording G. Akashi;H. Watanabe(ed.)
  2. 化學工學 v.48 no.6 テ一プ用 磁性鐵紛の開發 橋本順義
  3. Ferrite Proceeding of the ICF3 The Present and Future of Magnetic Recording Media G. Bate;H. Watanabe(ed.)(et al.)
  4. IEEE Trans. Mag. v.Mag-20 no.1 Characteristics and Application of Metal Tape R. Chubachi;N. Tamagawa
  5. ツ-エムツ一 高密度 メモリ 技術と材料 玉川惟正;中鉢良治
  6. 固體物理 v.11 no.19 室化鐵 磁性材料 喜多英治;田崎明
  7. 日本化學會誌 v.6 鐵室化物 超微粒子の合成と磁氣特性 田中隆夫;田川公照;田崎明
  8. IEEE. Trans. Mag v.Mag-15 no.6 Metal Using Ultra Fine Powder Prepared by Gas Evaporation Method A. Tasaki
  9. セラミックスの化學 柳田博明
  10. 窯業協會誌 v.83 no.9 TiCl₄-NH₃-H₂-N₂系氣相反應 による 窒化 チタン 微紛體 の合成 加藤昭夫;岩田正歲;北條純一;永野正光
  11. IEEE Trans. v.Mag-17 no.6 Recording Tape Using Iron Nitride Fine Powder A. Tasaki;T. Kusounose
  12. IEEE Trans. Mag v.Mag-20 no.1 Performances of Metal Pigment Tape with 600~700 Oe Coercivity S. Suzuki;J. Minegishi
  13. IEEE Trans. Mag. v.Mag-20 no.1 Magnetic Properties of Fe₄N and Fe pigment S. Suzuki;J. Minegishi
  14. IEEE Trans. Mag. v.Mag-20 no.1 Morphology of Iron Fine Particle T. Sueyoshi;H. Naono;M. Kawanami;M. Amemiya;H. Hayama
  15. 요업학회지 v.22 no.6 실리카 被着鐵粉末의 粒子形態 및 磁氣的特性에 미치는 영향(제1보) 吳在熙;金種植;柳炳煥
  16. 固體物理 v.7 no.9 室素雰圍氣中て蒸着した Fe 膜の磁性 高橋實
  17. 磁性體 ハンドブツグ 近角總信
  18. Jap. J. Appl. Phys. v.21 no.11 Synthesis of Fine Fe₄N Powder and Its Magnetic Characteristics K. Tagawa;E. Kita;A. Tasaki
  19. J. Mat. v.188 The Iron-Nitrogen System V. G. Paranjpe;M. Cohen;M.B. Bever;C. F. Floe
  20. 鳳山社刊 金屬材料工學 河上益天
  21. Ferrites Proceeding of the ICF3 The Formation of Iron Particles and Their Magnetic Properties Y. Tokuo;R. Horimoto;T. Kabuke;H. Morita;H. Watanabe(ed.)(et al.)