A Study on the Transparent Glass-Ceramics on the MgO-$Al_2O_3$-$SiO_2$ System

투명 결정화유리에 관한 연구 MgO-$Al_2O_3$-$SiO_2$계에 대하여

  • Published : 1991.05.01

Abstract

The composition of base glass was selected as MgO 8, Al2O3 24, SiO2 68 in weight percent. TiO2 and ZrO2 were added to the base glass to investigate their effects as nucleating agents. In the case of ZrO2 addition, the optimum temperature for nucleation, which was related to the precipitation of tetragonal ZrO2, was 80$0^{\circ}C$. The optimum growth condition for the crystal was 87$0^{\circ}C$ for 8 hrs, and the major crystal phases precipitated in the samples were $\beta$-quartz ss. and mullite. The light transmissivity turned out to be around 80 per cent. On the other hand, when the TiO2 was added, it was difficult to determine the nucleating temperature, because the samples turned easily into translucency during the heat treatment. Therefore, it was almost impossible to retain transparency in the samples. The light transmissivity was below 30 per cent.

Keywords

References

  1. Britis Patent 752243 S.D. Stookey
  2. J Mat. Sci. v.4 Transparent Glass Ceramics G.H. Beall;D.A. Duke
  3. Mat. Sci. & Eng. v.71 Transparent Glass Ceramics: Preparation, Characterization and properties A. Buch;M. Ish-shalom;R. Reisfeld;A. Kisilev
  4. J. Jap. Cer. So. v.88 no.1 Effect of Heat-treatment after Precipitation of ZrO₂on Transparency of Glass-Ceramics in ZnO-Al₂O₃-SiO₂System S. Yokoisi;H. Saito
  5. J. Am Cer. So. v.58 DTA and X-Ray Analysis Study of Nucleation and Crystallization of MgO-Al₂O₃-SiO₂Glasses Containing ZrO₂,TiO₂,CeO₂ W. Zdamewski
  6. J. Kor. Cer. So. v.26 no.3 Studies on the Transparently Crystallized Glass-On Li₂O-Al₂O₃-SiO₂Composition- Y.W. Park;J.E. Kim;S.J. Yon;J.H. Cho
  7. J. Kor. Cer. So. v.27 no.2 Studies on the Structure of Transparent Glass Ceramics YW. Park;W.K. Park;D.H. Kim
  8. Glass Ceramics P.W. McMillan
  9. J Mat. Sci. v.13 Cordierite Glass-Ceramics-Effect of TiO₂and ZrO₂Content on Phase Sequence during Heat Treatment T.I. Barry;JM. Cox;R. Morrell
  10. J. Am Cer. So. v.45 no.4 Determination of Percent Crystallinity of Partly Devitrified Glass by X-Ray Diffraction S.M. Ohlberg;D.W. Stricker
  11. Analytical Chemistry v.29 no.11 Reaction Kinetics in Differential Thermal Analysis H.E. Kissinger
  12. J Jap. Cer. So. v.96 no.2 Effect of Heat-treatment for Nucleation on the Crystallization of MgO-Al₂O₃-SiO₂Glass Containing TiO₂ X. Zhou;M. Yamane
  13. J Am Cer So. v.50 no.4 Crystallization and Chemical Strengthening of Stuffed β-Quartz Glass-Ceramics G.H. Beall;B.R. Karstetter;H.L. Rittler