A Study on Physical Properties of Epoxy Adhesives Modified with Polybutadiene Rubber

Polybutadiene 고무 변성 에폭시 접착제의 물성에 관한 연구

  • Hong, Suk-Pyo (Dept. of Chemical Tech., College of Eng., Chonbuk National University) ;
  • Choi, Sang-Goo (Dept. of Chemical Tech., College of Eng., Chonbuk National University)
  • 홍석표 (전북대학교 공과대학 공업화학과) ;
  • 최상구 (전북대학교 공과대학 공업화학과)
  • Published : 1991.09.30

Abstract

Epoxy resin and CTBN(carboxyl terminated butadiene acrylonitrile) rubber were reacted at $150^{\circ}C$. Epoxy mixtures containing reactant in a ratio $0{\sim}75%(wt%)$ of total liquid component were with dicyandiamide(DICY) at $130{\sim}200^{\circ}C$. Cure, thermal and adhesive properties were investigated in relation to rubber content, cure temperature, hardner content and promoter content. $CTBN{\times}13$ showed better properties in miscibility, curing time and adhesive strength. 2PZ-CNS was more excellent in Tg, and melamine was in adhesive strength. Adhesive strength represented best at rubber content $12{\times}15%$.

Keywords