Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Studies on the Evaluation of Hazadous Properties for Long Chain Alkyl Nitrates

장쇄 알킬 질산에스테르류의 위험성 평가에 관한 연구

  • Jeong, No-Hee (Dept. of Industrial Chemistry & Eng., Chungbuk National University) ;
  • Nam, Ki-Dae (Dept. of Industrial Chemistry & Eng., Chungbuk National University) ;
  • Kim, Hong-Soo (Dept. of Industrial Chemistry & Eng., Chungbuk National University) ;
  • Kim, Tae-Young (Dept. of Industrial Chemistry & Eng., Chungbuk National University)
  • 정노희 (충북대학교 공과대학 공업화학과) ;
  • 남기대 (충북대학교 공과대학 공업화학과) ;
  • 김홍수 (충북대학교 공과대학 공업화학과) ;
  • 김태영 (충북대학교 공과대학 공업화학과)
  • Published : 1991.11.30
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Abstract

Hazadous properties were evaluated for Alkyl nitrates such as hexyl nitrate, decyl nitrate, dodecyl nitrate and 2-methyl pentyl nitrate, 2-hexyl ethyl nitrate. The thermochemical properties such as heat of vaporization, boiling point, flash point and kinetic parameter for aliphatic nitrate were measured to determine the hazadous properties of these compounds. The boiling points and heat of vaporization increase as the increase of alkyl chain length in alkyl nitrates. Flash point is a linear function of boiling point as same as alkanes. The rate equation in isothermal decomposition are 1/2 order and compensation effect is found between logarithm of frequency factor the activation energy, then the decomposition preceeds with simlar reaction mechanism for each nitrate.

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