Joining of 8 mol% YSZ Solid Electrolyte and Perovskite LaMnO3

8 mol% YSZ 고체전해질과 페로프스카이트 $LaMnO_3$와의 접합

  • 김명철 (군산대학교 공과대학 재료공학과) ;
  • 박순자 (서울대학교 공과대학 무기재료공학과)
  • Published : 1992.05.01

Abstract

For the development of solid oxide fuel cell the joined interface formation between perovskite oxygen electrode and YSZ solid electrolyte is emphasized in the aspect of reducing the undisirable overpotential. The diffusion couple of LaMnO3 and YSZ was prepared by hot pressing at 130$0^{\circ}C$ in the flow of oxygen gas. The high temperature solid state reaction mechanism between LaMnO3 and YSZ is discussed on the basis of the cation composition profile through EDX analysis. The cation components in perovskite compound diffuse considerably into YSZ, while cations of YSZ diffuse little into perovskite.

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References

  1. Fuel Cell handbook Solid Oxide Electrolyte Fuel Cells A.J. Appleby;F.R. Foulkes
  2. Nippon Seramikkus Kyokai Gakujutsu Ronbunshi v.97 no.10 Hot Pressing of Perovskite LaNiO₃ M.C. Kim;S.J. Park;H. Haneda;A. Watanabe;J. Tanaka;S. Shirasaki
  3. J. Am. Ceram. Soc. v.75 no.2 Mechanism of Reaction betweem Lanthanum Manganite and Yttria-Stabilized Zirconia H. Taimatsu;K. Wada;H. Kaneko;H. Yamamura
  4. Solid State Ionics v.35 Kinetics Studies on the Reaction at the $La_{0.6}Ca_{0.4}MnO_3/YSZ$ Interface, as an SOFC Air Electrode K. Tsuneyoshi;K. Mori;A. Sawata
  5. Denki Kagaki v.57 no.8 Chemical Thermodynamic Considerations on Reactivity of Perovskite Oxide Electrodes with ZrO₂ H. Yokokawa;N. Sakai;T. Kawada;M. Dokiya
  6. Denki Kagaku v.57 no.8 Thermodynamic Analysis on Relation between Nonstoichiometry of LaMnO₃Perovskites and Their Reactivity with ZrO₂ H. Yokokawa;N. Sakai;T. Kawada;M. Dokiya
  7. J. Am. Ceram. Soc. v.73 no.3 Chemical Potential Digrams for Rare Earth-Transition Metal-Oxygen System:1, Ln-V-O and Ln-Mn-O System H. Yokogawa;T. Kawada;M. Dokiya
  8. Nippon Seramikkus Kyokai Gakujutsu Ronbunshi v.97 no.11 Sintering and Electrical Conductivity of $La_{1-x}Sr_xMnO_3$ K. Katayama;T. Ishihara;H. Ohta;S. Takeuchi;Y. Esaki;E. Enukai
  9. Solid State Ionics v.40;41 High Temperature Eletrical Conductivity of $La_{1-x}Sr_xMnO_{3-{\delta}}$ (x>0.5) M.C. Kim;S.J. Park;H. Haneda;S. Shirasaki
  10. Advanced Materials in Catalysts R.J.H. Voorhoeve
  11. Nippon Kagakukai 53th Nenkai S. Shitayama;S. Mizusaki
  12. Denki Kagaku v.58 no.2 Chemical Thermodynamic Considerations on Chemical Stability of $(La_{1-x}Sr_x)_yMnO_3$ Perovskite Air Electrode against Reaction with ZrO₂Electrolyte in SOFC H. Yokogawa;N. Sakai;T. Kawada;M. Dokiya