Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Continuous Processing of Monodispersed Zirconia Powders

초음파 혼합 연속공정에 의한 단분산 지르코니아 분체의 합성

  • Rhee, Jhun (Dept. of Ceramic Eng., Inha Univ) ;
  • Jo, Dong-Soo (Dept. of Ceramic Eng., Inha Univ)
  • 이전 (인하대학교 무기재료공학과) ;
  • 조동수 (인하대학교 무기재료공학과)
  • Published : 1992.12.01
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Abstract

Continuous synthesis process for monodispersed zirconia powders with ultrasonic wave mixing was developed. Reactant solutions were flowed through a T-tube with small diameter and then mixed in a microscale with ultrasonification. Reaction and aging were followed during the mixed solution of reactants is in plug flowing through a narrow long teflon tubing. Zr(n-OC4H9)4 in ethanol and H2O in ethanol were used as reactants. From this process monodispersed, spherical, non-agglomerated, singlet hydrated zirconia powders with 0.6 $\mu\textrm{m}$ average size were obtained. Geometrical standard deviation of the particle size distribution was less than 1.2 with ultrasonic mixing, and the geometrical standard deviation was not affected by the flow rate of the reactants.

Keywords

References

  1. Better Ceramics through Chemistry Synthesis, Characterization and Processing of Monosized Ceramics Powders B. Fegly;E.A. Barriger;C.J. Brinker(ed.);D.E. Clark(ed.);D.R. Ulrich(ed.)
  2. J. Coll. Interf. Sci. v.26 Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range W, Stober;A. Fink
  3. J. Am. Ceram. Soc. v.67 Preparation of SiO₂Glass from Model Powder Compacts;I, Formation and Characterization of Powders, Suspensions and Green Compacts M.D. Sacks;T.Y. Tseng
  4. Science of Ceramics v.14 Controlled Growth of Monodispersed Spherical Silica by a New Synthesis Process K. Yoshizawa;Y. Sugoh;Y. Ochu
  5. J. Ceram. Soc. Jpn. v.96 no.7 Growth of Seeded Silica from Si(OEt)₄in Ethanol K. Nakanish;Y. Takamiya
  6. J. Non-Cryst. Solids v.104 Preparation of Monodisperse Silica Particles;Contol of Size and Mass Fraction G.H. Bogush;M.A. Tracy;C.F. Zukoski IV
  7. J. Ceram. Soc. Jpn. v.93 no.5 Synthesis of Monodispersed Titania Fine Particles by Hydrolysis of $Ti(OC_{2}H_{5})$ T. Ikemoto;K Uematsu;N. Mizutani;M. Kato
  8. J. Mater. Sci. v.21 Formation of Monodispersed $Ta_{2}O_{5}$ Powders T. Ogihara;T. Ikemoto;N. Mizutani;M. Kato
  9. J. Ceram. Soc. Jpn. v.94 no.1 Preparation of Monodispersed Spherical Ta₂O5·nH₂O Particles with Controlled Size K. Nakanishi;Y. Takamiya;T. Shimohira
  10. J. Chem. Soc. v.73 Zirconium Alkoxides D.C. Bradley;W. Wardlaw
  11. J. Am. Ceram. Soc. v.48 no.7 Preparation of Ultra High Purity Submicron Refractory Oxides K.S. Mazdiyasni;C.T. Lynch;J.S. Smith
  12. Ceram. Int. v.8 no.2 Powder Synthesis from Metal Organic Precursors K.S. Mazdiyasm
  13. Pure & Appl. Chem. v.50 Preparation and Properties of Monodispersed Colloidal Metal Hydrous Oxides E. Matijevic
  14. Acc. Chem. Res. v.14 Monodispersed Metal (Hydrous) Oxides-A Fascinating Field of Colloid Science E. Matijevic
  15. Am. Ceram. Soc. Bull. v.64 no.8 Processing and Characterization of ZrO₂and Y-doped ZrO₂Powders B.Fegley, Jr.;P. White;H.K. Bowen
  16. J. Ceram. Soc. Jap. v.93 no.9 Synthesis of Monodispersed Zirconia Fine Particle T. Ikemoto;N. Mizutani;M. Kato;Y. Mitarai
  17. Ceram. Int. v.13 Processing of Monodispersed ZrO₂Powders T. Ogihara;N. Mizutani;M. Kato
  18. J. Mater. Sci. v.21 Zirconium Oxides Formed by Hydrolytic Condensation of Alkoxides and Parameters that Affect Their Morphology B.E. Yoldas
  19. M.S. Thesis,Inha University Synthesis of Zirconia Powders for High Performance Ceramics Hee-Tai Eun;Jhun Rhec
  20. J. Ceram. Soc. Jpn. v.99 no.4 Influence of Alcoholic Solvents on the Formation of Monodispersed Particles by Hydrolysis of Zirconium Tetra-n-Butoxide Seok-Keun Lee;Masaki Ikeda;Nobuyasu Mizutani
  21. J. Kor. Ceram. Soc. v.28 no.2 Synthesis of Monodispersed Zirconia Powder by Hydrolysis of Zirconium Alkoxides J. Rhee;D.S. Jo
  22. J. Kor. Ceram. Soc. v.28 no.8 Effect of HPC Dispersant on Synthesis of Monodispersed Hydrated Zirconia Powder by Hydrolysis of Zr-n-butoxide J. Rhee;D S. Jo
  23. Chem. Eng. Sci. v.39 no.12 Continuous Precipitation of Monosized Particles with a Packed Bed Crystallizer T.A. Ring
  24. Am. Ceram. Soc. Bull. v.66 no.10 Continuous Production of Narrow-Sized and Unagglomerated TiO₂Powders J.H. Jean;D.M. Goy;T.A. Ring
  25. Mater. Sci. Eng. v.78 A Chemical Reactor System for TiO₂and ZrO₂Powder Synthesis A. van Zyl;P.M. Smith;A.I. Kingon
  26. J. Am. Ceram. Soc. v.72 no.9 Continuous Processing of Nomodispersed Titania Powders T. Ogthara;M. Ikeda;M. Kato;N. Mizutani
  27. Chemical Reaction Engineering O. Levenspiel