Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation and Structure of $CH_2CH_2OOCCHCH_2SnCl_3$

  • Jung Ok-Sang (Inorganic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Lee Young-A (Inorganic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Jeong, Jong Hwa (Inorganic Chemistry Laboratory, Korea Institute of Science and Technology) ;
  • Sohn Youn Soo (Inorganic Chemistry Laboratory, Korea Institute of Science and Technology)
  • Published : 1992.08.20
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Abstract

A new estertin, $CH_2CH_2OOCCHCH_2SnCl_3$, was prepared and its structure was determined by X-ray crystallography ($P2_12_12_1$; a = 9.439(l), b = 9.601(l), c = 10.779(I) $\AA$, Z = 4) and refined to R = 0.0356. The coordination geometry around the tin atom approximates to a trigonal bipyramid with the intramolecularly coordinated oxygen O(1), (Sn-O(1), $2.482(6){\AA})$ and Cl(2) occupying mutually trans positions (O(1)-Sn-Cl((2), $176.4(2)^{\circ}$).

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References

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  1. TIN ORGANOMETALLIC COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA: PART 1. MONOMERIC DERIVATIVES vol.23, pp.1, 1992, https://doi.org/10.1515/mgmc.2000.23.1-2.1
  2. Experimental and ab initio structural study of the ketotin compounds, X3SnCR2CH2COMe: crystal structures of X3SnCMe2CH2COMe (X = Cl an vol.19, pp.3, 1992, https://doi.org/10.1002/aoc.852