한국섬유공학회지 (Textile Science and Engineering)

  • 제30권8호
  • /
  • Pages.578-586
  • /
  • 1993
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

Hexafluorobisphenol A 단위를 함유하는 Poly(arylene Etherketone)의 구조와 물성

Structure and Properties of Poly(arylene Etherketone)s Containing Hexafluorobisphenol A Unit

  • 이철주 (한국과학기술연구원 섬유고분자연구실) ;
  • 손태원 (한국과학기술연구원 섬유고분자연구실, 서울대학교 공과대학 섬유고분자공학과) ;
  • 하완식
  • 발행 : 1993.08.01

⟨ 이전 논문 다음 논문 ⟩

초록

Poly(arylene etherketone) copolymers, modified by introducing bulky groups into the linking units of aromatic rings of polyetheretherketone. were prepared and their physical properties were investigated. The copolymers were synthesized by nucleophilic substitution reaction of 4.4'-difluorobenzophenone with hydroquinone(HQ) and second diol component. hexafluorobisphenol A(HFBA). 10 species of the copolymers were prepared in various ratios of HQ to HFBA. The btnzophenone-HFBA units in the copolymers hindered the benzophenone-HQ units from crystallization and were located in the amorphous regions of the copolymers Through the analysis of activation energies and frequency factors for the thermal decomposition of the copolymers. Thermal stability and rates of thermal decomposition were found to have no correlation with the copolymer composition.

키워드

참고문헌

  1. Sumitomo Gakaku v.1982-Ⅰ T.Saito;K.Asai;H.Hayashida
  2. Encyclopedia of Polymer Science and Technology(2nd Ed.) v.12 H.F.Mark;N.M.Bikales;C.G.Overberger;G.Menges(ed.)
  3. 工業材料(日) v.31 I.Hiroshi
  4. Polym. Commun. v.25 N.T.Wakelyn
  5. J. Appl. Polym. Sci. v.36 S.A.Thomson;R.J.Farris
  6. Polymer v.25 E.J.Stober;J.C.Seferis;J.D.Keenan
  7. J. Polym. Sci. : Part C : Polym. Lett. v.25 N.T.Wakelyn
  8. Polym. New. v.9 R.B.Rigby
  9. Polym. Eng. Sci. v.25 O.B.Searle;R.H.Pfeiffer
  10. Polym. Prep. v.28 G.D.Lyle;M.J.Jurek;D.K.Mohanty;S.D.Wu;J.C.Hedrick;J.E.McGrath
  11. Polymer v.27 T.Sasuga;M.Hagiwara
  12. J. Appl. Polym. Sci. v.32 C.M.Chan;S.Venkatraman
  13. Polymer v.21 P.C.Dawson;D.J.Blundell
  14. Polymer v.29 P.M.Hergenrother;B.J.Jensen;S.J.Havens
  15. 한국섬유공학회지 v.30 이철주;손태원;하완식
  16. Polym. Commun. v.24 D.R.Rueda;F.Ania;A.Richardson;I.M.Ward;F.J.B.Calleja
  17. Polymer v.30 L.C.Lopez;G.L.Wilkes
  18. Polymer v.30 J.Devaux;D.Daoust;R.Legras;J.M.Dereppe;E.Nield
  19. Polymer v.29 J.N.Clark;N.R.Jagannathan;F.G.Herring
  20. Polymer v.18 T.E.Attwood;D.A.Barr;G.G.Feassy;V.J.Leslie;A.B.Newton;J.B.Rose
  21. Makromol. Chem. Rapid. Commun. v.6 M.Ueda
  22. J. Polym. Sci. : Polym. Chem. Ed. v.23 T.Ogawa;C.S.Marvel
  23. J. Polym. Sci. v.6 Y.Iwakura;K.Uno;T.Takiguchi
  24. Polymer v.26 J.Devaux;D.Delimoy;D.Daoust;R.Legras;J.P.Mercier;C.Strazielle;E.Nield
  25. U.S.Patent, 4,320,224 J.B.Rose;P.A.Staniland
  26. Polymer v.27 A.V.Fratini;E.M.Cross;R.B.Whitaker;W.W.Adams
  27. J. Mat. Sci. v.22 A.J.Waddon;M.J.Hill;A.Keller
  28. Polym. Commun. v.25 J.N.Hay;D.J.Kemmish;J.I.Langford;I.M.Ward
  29. Macromolecules v.19 A.J.Lovinger;D.D.Davis
  30. J. Polym. Sci. : Polym. Chem. Ed. v.21 J.Lee;C.S.Marvel
  31. Polymer v.27 S.Kumar;D.P.Anderson;W.W.Adams
  32. J. Res. Nat. Bur. Stand. v.60 L.A.Wall;R.E.Florin
  33. J. Res. Nat. Bur. Stand. v.70A no.6 J.H.Flynn;L.A.Wall
  34. J. Res. Nat. Bur. Stand. v.60 J.H.Flynn;L.A.Wall
  35. Polym. Eng. Sci. v.29 M.Day;L.D.Cooney;D.M.Wiles
  36. Polym. Eng. Sci. v.26 W.E.Moddenman;W.C.Bowling;E.E.Tibbitts;R.B.Whitaker
  37. J. Appl. Polym. Sci. v.38 M.Day;J.D.Cooney;D.M.Wiles
  38. J. Appl. Polym. Sci. v.37 I.K.Anmed;M.A.M.Rashid